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Control of Polymorphism of Metal–Organic Frameworks Using Mixed-Metal Approach

机译:用混合金属方法控制金属 - 有机框架多态性

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src="http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cgdefu/2018/cgdefu.2018.18.issue-1/acs.cgd.7b01193/20171227/images/medium/cg-2017-011938_0007.gif">Herein, we report the influence of iron(III) on the crystallization of chromium(III) terephthalate metal–organic framework. The selective phase formation of polymorphs MIL-101 and MIL-88B can be systematically controlled by varying the concentration of metal-cationic competitor, iron(III). The addition of iron(III) affects not only the selective phase formation but also the morphology and crystallinity of chromium(III) terephthalate MOF. This investigation clearly indicates the crystal growth tailoring of polymorphic MOFs by means of the second metal ionic competitor.
机译:src =“http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cgdefu/2018/cgdefu.2018.18.issue-1/acs.cgd.7b01193/20171227/images/medium /c-2017-011938_0007.gif“stice”,我们报告了铁(III)对铬(III)对苯二甲酸酯金属 - 有机骨架结晶的影响。 通过改变金属阳离子竞争对手,铁(III)的浓度,可以系统地控制多晶型密耳MIL-101和MIL-88B的选择性相形成。 添加铁(III)不仅影响选择性相形成,而且影响铬(III)对苯二甲酸酯的形态和结晶度。 该研究清楚地表明,通过第二金属离子竞争对手,多态MOF的晶体生长剪裁。

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  • 来源
    《Crystal growth & design》 |2018年第1期|共6页
  • 作者单位

    School of Energy Science and Engineering and Frontier Research Center (FRC) Vidyasirimedhi Institute of Science and Technology 555 Moo 1 Payupnai Wangchan Rayong 21210 Thailand;

    School of Energy Science and Engineering and Frontier Research Center (FRC) Vidyasirimedhi Institute of Science and Technology 555 Moo 1 Payupnai Wangchan Rayong 21210 Thailand;

    School of Energy Science and Engineering and Frontier Research Center (FRC) Vidyasirimedhi Institute of Science and Technology 555 Moo 1 Payupnai Wangchan Rayong 21210 Thailand;

    National Nanotechnology Center (NANOTEC) National Science and Technology Development Agency (NSTDA) 111 Thailand Science Park Pahonyothin Rd. Klong Laung Pathumthani 12120 Thailand;

    National Nanotechnology Center (NANOTEC) National Science and Technology Development Agency (NSTDA) 111 Thailand Science Park Pahonyothin Rd. Klong Laung Pathumthani 12120 Thailand;

    Chair of Inorganic and Metal?Organic Chemistry Department of Chemistry Technical University of Munich Lichtenbergstr. 4 D-85748 Garching Germany;

    School of Energy Science and Engineering and Frontier Research Center (FRC) Vidyasirimedhi Institute of Science and Technology 555 Moo 1 Payupnai Wangchan Rayong 21210 Thailand;

    School of Energy Science and Engineering and Frontier Research Center (FRC) Vidyasirimedhi Institute of Science and Technology 555 Moo 1 Payupnai Wangchan Rayong 21210 Thailand;

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  • 正文语种 eng
  • 中图分类 晶体学;
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