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首页> 外文期刊>Crystal growth & design >Modulating Anticancer Potential by Modifying the Structural Properties of a Family of Zinc Metal–Organic Chains Based on 4-Nitro-1H-pyrazole
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Modulating Anticancer Potential by Modifying the Structural Properties of a Family of Zinc Metal–Organic Chains Based on 4-Nitro-1H-pyrazole

机译：通过基于4-NITRO-1 -Pyrazole改变锌金属 - 有机链的结构性能来调节抗癌潜力。

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摘要

We have synthesized a novel family of metal–organic chains based on 4-nitro-1 H -pyrazole linker and zinc as metal center. We report the formation of these coordination polymers using hydrothermal routes with water as solvent. These materials display one-dimensional structures with major structural modifications from minimal synthetic variations. What is more interesting, we have carried out antitumor measurements, and we have related these properties with the structural networks. To the best of our knowledge, these materials constitute the first examples of polymeric structures for 4-NO_(2)-pz ligands. NMR and MS spectrometry were used to verify the characterization of the metal complexes in solution to corroborate that these materials are present in the biological assays.
机译：我们已经合成了基于4-硝基-1h-吡唑连接物和锌作为金属中心的新型金属有机链家族。 我们报告了使用用水作为溶剂的水热线形成这些配位聚合物。 这些材料显示一维结构，具有从最小合成变化的主要结构修改。 更有趣的是，我们进行了抗询问测量，我们将这些属性与结构网络相关联。 据我们所知，这些材料构成了4-NO_（2）-PZ配体的聚合物结构的第一个实例。 NMR和MS光谱法用于验证溶液中金属配合物的表征，以证实这些材料存在于生物测定中。

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  • 来源
    《Crystal growth & design》 |2018年第2期|共10页
  • 作者

    Belén Fernández; Ignacio Fernández; Javier Cepeda; Marta Medina-O’Donnell; Eva E. Rufino-Palomares; álvaro Raya-Barón; Santiago Gómez-Ruiz; Amalia Pérez-Jiménez; José Antonio Lupiá?ez; Fernando J. Reyes-Zurita; Antonio Rodríguez-Diéguez;

  • 作者单位

    Departament of Inorganic Chemistry C/Severo Ochoa s/n University of Granada 18071 Granada Spain;

    Department of Chemistry and Physics Research Centre for Agricultural and Food Biotechnology (BITAL) University of Almería Ctra. Sacramento s/n 04120 Almería Spain;

    Department of Applied Chemistry University of The Basque Country (UPV/EHU) 20018 San Sebastián Spain;

    Department of Biochemistry Severo Ochoa s/n University of Granada 18071 Granada Spain;

    Department of Biochemistry Severo Ochoa s/n University of Granada 18071 Granada Spain;

    Department of Chemistry and Physics Research Centre for Agricultural and Food Biotechnology (BITAL) University of Almería Ctra. Sacramento s/n 04120 Almería Spain;

    Department of Biology and Geology Physics and Inorganic Chemistry Rey Juan Carlos University c/Tulipán s/n 28933 Móstoles (Madrid) Spain;

    Department of Biochemistry Severo Ochoa s/n University of Granada 18071 Granada Spain;

    Department of Biochemistry Severo Ochoa s/n University of Granada 18071 Granada Spain;

    Department of Biochemistry Severo Ochoa s/n University of Granada 18071 Granada Spain;

    Departament of Inorganic Chemistry C/Severo Ochoa s/n University of Granada 18071 Granada Spain;

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  • 正文语种 eng
  • 中图分类 晶体学;
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