Vacuum-Mediated Single-Crystal-to-Single-Crystal (SCSC) Transformation in Na-MOFs: Rare to Novel Topology and Activation of Nitrogen in Triazole Moieties

ShagufiNaz Ansari; Sanjay K. Verma; Aleksandr A. Garin; Shaikh M. Mobin

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Vacuum-Mediated Single-Crystal-to-Single-Crystal (SCSC) Transformation in Na-MOFs: Rare to Novel Topology and Activation of Nitrogen in Triazole Moieties

机译：真空介导的Na-Mofs的单晶单晶（SCSC）转化：罕见的三唑部分中的新型拓扑和氮的活化

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We report a rare example of facile in situ synthesis of Na-MOF1 that undergoes vacuum-mediated single-crystal-to-single-crystal (SCSC) transformations from rare parallel polycatenated kgd nets to new and novel 3-periodic 3,3,12-c net topology (named smm1). Further, SCSC transformation of Na-MOF1 to Na-MOF2 reveals activation of N–N atoms in 1,2,3-triazole unit. Na-MOF1 and Na-MOF2 were authenticated by single-crystal X-ray studies, and the bulk was confirmed by powder X-ray diffraction studies.

机译：我们报告了本地合成的罕见实例，其对Na-Mof1进行了真空介导的单晶单晶（SCSC）转化，从罕见的平行聚催化KGD网转变为新的和新的3-周期3,3,12 -C净拓扑（命名为SMM1）。此外，Na-MOF1至Na-MOF2的SCSC转化揭示了1,2,3-三唑单元中N-N原子的活化。通过单晶X射线研究进行鉴定Na-Mof1和Na-Mof2，并通过粉末X射线衍射研究证实了体积。

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《Crystal growth & design》 |2018年第3期|共6页
作者
ShagufiNaz Ansari; Sanjay K. Verma; Aleksandr A. Garin; Shaikh M. Mobin;
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Discipline of Chemistry Center for Biosciences and Bio-Medical Engineering and Discipline of Metallurgy Engineering and Materials Science Indian Institute of Technology Indore Simrol Khandwa Road Indore 453552 India;

Discipline of Chemistry Center for Biosciences and Bio-Medical Engineering and Discipline of Metallurgy Engineering and Materials Science Indian Institute of Technology Indore Simrol Khandwa Road Indore 453552 India;

Samara Center for Theoretical Materials Science (SCTMS) Samara University Samara 443011 Russia;

Discipline of Chemistry Center for Biosciences and Bio-Medical Engineering and Discipline of Metallurgy Engineering and Materials Science Indian Institute of Technology Indore Simrol Khandwa Road Indore 453552 India;

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1. Vacuum-Mediated Single-Crystal-to-Single-Crystal (SCSC) Transformation in Na-MOFs: Rare to Novel Topology and Activation of Nitrogen in Triazole Moieties [J] . ShagufiNaz Ansari, Sanjay K. Verma, Aleksandr A. Garin, Crystal growth & design . 2018,第3期

机译：真空介导的Na-Mofs的单晶单晶（SCSC）转化：罕见的三唑部分中的新型拓扑和氮的活化
2. Anion triggered and solvent assisted structural diversity and reversible single-crystal-to-single-crystal (SCSC) transformation between 1D and 2D coordination polymers [J] . Tripathi Sarita, Srirambalaji Renganathan, Patra Samir, CrystEngComm . 2015,第46期

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3. A series of two-dimensional microporous triazole-functionalized metal-organic frameworks with the new multi-dentate ligand 1-(4-aminobenzyl)-1,2,4-triazole: single-crystal-to-single-crystal transformation, structural diversity and luminescent sensing [J] . Wang You You, Jin Qing, Liu Shi Xin, RSC Advances . 2015,第44期

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4. 1,2,3-triazoles as X-factor in gold(I) activation of challenging C-C triple bond transformations. [D] . Wang, Qiaoyi. 2014

机译：1,2,3-三唑作为X因子在具有挑战性的C-C三键转化的金（I）活化中。
5. Joint Experimental and Theoretical Studies of Two Cu(II) Complexes with a 1,2,3-Triazole Derivative as Ligand: SCSC Transformation and Tunable Magnetic Properties [O] . -1

机译：用1,2,3-三唑衍生物作为配体的三种Cu（II）配合物的联合实验和理论研究：SCSC转化和可调谐磁性

Vacuum-Mediated Single-Crystal-to-Single-Crystal (SCSC) Transformation in Na-MOFs: Rare to Novel Topology and Activation of Nitrogen in Triazole Moieties

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