Centrosymmetric (NH4)(2)SbCI(SO4)(2) and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

He Fangfang; Wang Qian; Hu Cuifang; He Wen; Luo Xueying; Huang Ling; Gao Daojiang; Bi Jian; Wang Xin; Zou Guohong

首页> 外文期刊>Crystal growth & design >Centrosymmetric (NH4)(2)SbCI(SO4)(2) and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

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Centrosymmetric (NH4)(2)SbCI(SO4)(2) and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

机译：Centroosymmetric（NH4）（2）SBCI（SO 4）（2）和非Centroosymmetric（NH4）SbCl2（SO4）：氢键相互作用和孤立阳离子对框架结构和宏观中心的协同作用

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Two new antimony sulfate chlorides named (NH4)(2)SbCl(SO4)(2) and (NH4)SbCl2(SO4) were successfully synthesized through solvent-free synthesis method. (NH4)(2)SbCl(SO4)(2) exhibits a three-dimensional framework constructed of [SbCl(SO4)(2)](2-) chains and NH4+ ions. And the NH4+ cations play the role of charge balance and provide the hydrogen bond constructed with oxygen atoms. (NH4)-SbCl2(SO4) shows a two-dimensional layer structure that is composed of the regularly stacked [SbCl2(SO4)](-) chains via hydrogen-bonding interactions. Both of the titled compounds possess the same chemical composition and the similar Sb-Cl-SO4 chains, while hydrogen-bonding interactions and lone-pair cations play the synergistic effect on the framework structures and macroscopic centricities resulting in that the (NH4)(2)SbCl(SO4)(2) is centrosymmetric and the (NH4)SbCl2(SO4) is non-centrosymmetric (NCS). Powder second harmonic generation (SHG) measurements indicated that the NCS compound (NH4)SbCl2(SO4) is type I phase-matchable and exhibits SHG responses of similar to 1.7 times that of KH2PO4.

机译：通过无溶剂合成方法成功合成了两种名为（NH4）（2）SBCl（SO4）（2）和（SO4）的新的抗硫酸氯化物。（NH4）（2）SbCl（SO 4）（2）表现出由[SbCl（SO 4）（2）]（2-）链和NH 4 +离子构成的三维框架。 NH4 +阳离子发挥了电荷平衡的作用，并提供了用氧原子构成的氢键。（NH4）-SBCL2（SO4）示出了通过氢键相互作用的定期堆叠的[SBCL2（SO 4）]（ - ）链组成的二维层结构。所有标题的化合物都具有相同的化学组成和类似的Sb-Cl-SO4链，而氢键相互作用和孤牌阳离子在框架结构和宏观中心起作用的协同作用，导致（NH4）（2 ）SbCl（SO 4）（2）是亚里索二元，（NH 4）SBCL2（SO 4）是非亚聚对称（NCS）。粉末二次谐波产生（SHG）测量表明，NCS化合物（NH4）SBCL2（SO 4）是I类相匹配的，并且表现出类似于KH2PO4的1.7倍的SHG响应。

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来源
《Crystal growth & design》 |2018年第10期|共9页
作者
He Fangfang; Wang Qian; Hu Cuifang; He Wen; Luo Xueying; Huang Ling; Gao Daojiang; Bi Jian; Wang Xin; Zou Guohong;
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作者单位

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Univ Coll Chem Chengdu 610064 Peoples R China;

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Normal Univ Coll Chem &

Mat Sci Chengdu 610068 Sichuan Peoples R China;

Sichuan Univ Coll Chem Chengdu 610064 Peoples R China;

Sichuan Univ Coll Chem Chengdu 610064 Peoples R China;

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正文语种 eng
中图分类晶体学;
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1. Centrosymmetric (NH4)(2)SbCI(SO4)(2) and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities [J] . He Fangfang, Wang Qian, Hu Cuifang, Crystal growth & design . 2018,第10期

机译：Centroosymmetric（NH4）（2）SBCI（SO 4）（2）和非Centroosymmetric（NH4）SbCl2（SO4）：氢键相互作用和孤立阳离子对框架结构和宏观中心的协同作用
2. Monomers, chains and layers of [Pt-2(SO4)(4)] units in the crystal structures of the platinum(III) sulfates (NH4)(2)[Pt-2(SO4)(4)(H2O)(2)], K-4[Pt-2(SO4)(5)] and Cs[Pt-2(SO4)(3)(HSO4)] [J] . Pley M, Wickleder MS European journal of inorganic chemistry . 2005,第3期

机译：硫酸铂（III）（NH4）（2）[Pt-2（SO4）（4）（H2O）（2）的晶体结构中的[Pt-2（SO4）（4）]单元的单体，链和层）]，K-4 [Pt-2（SO4）（5）]和Cs [Pt-2（SO4）（3）（HSO4）]
3. Jahn-Teller ordering in manganese(III) fluoride sulphates. I. Crystal structures of A(2)[MnF3(SO4)] (A = Rb, NH4, Cs) [German] [J] . Klein U., Massa W. Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第5期

机译：Jahn-Teller订购硫酸锰（III）。 I. A（2）[MnF3（SO4）]的晶体结构（A = Rb，NH4，Cs）[德语]
4. Interactions between glycerol, PEG-200 and (NH4)2 SO4 in the stability of heterologous cutinase [O] . Gomes Daniela S., Matamá Maria Teresa, Paulo Artur Cavaco, 2013

机译：甘油，PEG-200和（NH4）2 SO4在异源角质酶稳定性中的相互作用

Centrosymmetric (NH4)(2)SbCI(SO4)(2) and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

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