Pt/Pd and I/Br Isostructural Exchange Provides Formation of C-I center dot center dot center dot Pd, C-Br center dot center dot center dot Pt, and C-Br center dot center dot center dot Pd Metal-Involving Halogen Bonding

Baykov Sergey V.; Dabranskaya Uladzislava; Ivanov Daniil M.; Novikov Alexander S.; Boyarskiy Vadim P.

首页> 外文期刊>Crystal growth & design >Pt/Pd and I/Br Isostructural Exchange Provides Formation of C-I center dot center dot center dot Pd, C-Br center dot center dot center dot Pt, and C-Br center dot center dot center dot Pd Metal-Involving Halogen Bonding

【24h】

Pt/Pd and I/Br Isostructural Exchange Provides Formation of C-I center dot center dot center dot Pd, C-Br center dot center dot center dot Pt, and C-Br center dot center dot center dot Pd Metal-Involving Halogen Bonding

机译：PT / PD和I / BR IsostraturalOnteract提供C-I中心点中心DOT中心点PD，C-BR中心DOT中心点中心点PT，C-BR中心点中心点中心点PD PD金属粘合剂

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Complexes trans-[MCl2(NCNMe2)(2)] (M = Pt 1, Pd 2) were cocrystallized with CHBr3 and CHI3, forming 1:2 adducts isomorphic with previously reported trans-[PtCl2(NCNMe2)(2)]center dot 2CHI(3). In all cases, the C-X center dot center dot center dot M (X = Br, I; M = Pd, Pt) metal-involving halogen bonding together with numerous chloride-halomethane halogen and hydrogen bonds were identified by single-crystal XRD experiments. Further DFT calculations and topological analysis of the electron density distribution within the framework of QTAIM method at the M06/DZP-DKH level of theory confirmed the existence of these interactions and their noncovalent nature. Estimated energies of such contacts vary from 1.6 to 3.1 kcal/mol.

机译：复合物反式[Mcl 2（NCNME2）（2）]（M = Pt 1，Pd 2）用Chbr3和Chi3将1：2加入同性恋与先前报道的反式 - [PtCl2（NCNME2）]中心点 2chi（3）。在所有情况下，通过单晶XRD实验鉴定了C-X = Br，I; M = Pd，Pt）金属涉及与无数氯化卤素卤素和氢键的卤素键合。在M06 / DZP-DZH-DTKH理论水平的Qtaim方法框架内的进一步DFT计算和电子密度分布的拓扑分析证实了这些相互作用及其非价性质的存在。这种接触的估计能量在1.6到3.1 kcal / mol之间变化。

著录项

来源
《Crystal growth & design》 |2018年第10期|共8页
作者
Baykov Sergey V.; Dabranskaya Uladzislava; Ivanov Daniil M.; Novikov Alexander S.; Boyarskiy Vadim P.;
展开▼
作者单位

St Petersburg State Univ Inst Chem Univ Skaya Nab 7-9 St Petersburg 199034 Russia;

St Petersburg State Univ Inst Chem Univ Skaya Nab 7-9 St Petersburg 199034 Russia;

St Petersburg State Univ Inst Chem Univ Skaya Nab 7-9 St Petersburg 199034 Russia;

St Petersburg State Univ Inst Chem Univ Skaya Nab 7-9 St Petersburg 199034 Russia;

St Petersburg State Univ Inst Chem Univ Skaya Nab 7-9 St Petersburg 199034 Russia;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Pt/Pd and I/Br Isostructural Exchange Provides Formation of C-I center dot center dot center dot Pd, C-Br center dot center dot center dot Pt, and C-Br center dot center dot center dot Pd Metal-Involving Halogen Bonding [J] . Baykov Sergey V., Dabranskaya Uladzislava, Ivanov Daniil M., Crystal growth & design . 2018,第10期

机译：PT / PD和I / BR IsostraturalOnteract提供C-I中心点中心DOT中心点PD，C-BR中心DOT中心点中心点PT，C-BR中心点中心点中心点PD PD金属粘合剂
2. Metal-Involving Bifurcated Halogen Bonding C-Br center dot center dot center dot eta(2)(Cl-Pt) [J] . Dabranskaya Uladzislava, Ivanov Daniil M., Novikov Alexander S., Crystal growth & design . 2019,第2期

机译：金属涉及分叉的卤素键C-BR中心点中心DOT中心DOT ETA（2）（CL-PT）
3. M-X center dot center dot center dot X '-C halogen-bonded network formation in MX2(4-halopyridine)(2) complexes (M = Pd, Pt; X = Cl, I; X ' = Cl, Br, I) [J] . Zordan F, Brammer L Crystal growth & design . 2006,第6期

机译：M-X中心点中心点中心点X'-C在MX2（4-卤代吡啶）（2）配合物中形成卤素键网络（M = Pd，Pt; X = Cl，I; X'= Cl，Br，I）
4. Comparative investigation of quantum-dot-like localization centers in InGaN quantum well and quantum dot structures [C] . K. Sebald, H. Lohmeyer, J. Gutowski, Symposium on GaN, AIN, InN and Related Materials . 2006

机译：IngaN量子阱和量子点结构中量子点状定位中心的比较研究
5. CPDICenter: Web-based virtual construction project document information center in support of claims preparation. [D] . Hammad, Mamoon Mohammad. 2001

机译：CPDICenter：基于Web的虚拟施工项目文件信息中心，可支持索赔准备。
6. Low rate of non-compliance to antituberculous therapy under the banner of directly observed treatment short course (DOTS) strategy and well organized retrieval system: a call for implementation of this strategy at all DOTS centers in Saudi Arabia [O] . Liaqat Ali Chaudhry, Jaffar Al-Tawfiq, Ebtesam Ba-Essa, 2015

机译：在直接观察到的短期治疗（DOTS）策略和组织良好的检索系统的旗帜下抗结核治疗的不合规率低：呼吁在沙特阿拉伯的所有DOTS中心实施该策略
7. 2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds [O] . Wardell, S M S V, Ferreira, M D, de Souza, M V N, 2006

机译：2,4-二氟苯甲醛苯甲酰and和2,4-二氯苯甲醛苯甲酰Z在120 K下具有Z'= 2的同构结构：由NH中心点中心点中心点O，CH中心点中心点中心点O和CH中心点中心组成的复合片点中心点pi（芳烃）氢键

Pt/Pd and I/Br Isostructural Exchange Provides Formation of C-I center dot center dot center dot Pd, C-Br center dot center dot center dot Pt, and C-Br center dot center dot center dot Pd Metal-Involving Halogen Bonding

摘要

著录项

相似文献

相关主题

期刊订阅