Assembly of Oxygen-Stuffed Supertetrahedral T3-SnOS Clusters into Open Frameworks with Single Sn2+ Ion as Linker

Lv Jing; Wang Wei; Zhang Li; Xue Chaozhuang; Hu Dandan; Wu Tao

首页> 外文期刊>Crystal growth & design >Assembly of Oxygen-Stuffed Supertetrahedral T3-SnOS Clusters into Open Frameworks with Single Sn2+ Ion as Linker

【24h】

Assembly of Oxygen-Stuffed Supertetrahedral T3-SnOS Clusters into Open Frameworks with Single Sn2+ Ion as Linker

机译：将氧填充的超级去型T3-SNOS集团组装成具有单个SN2 +离子的开放式框架，作为接头

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Here three new types of cluster-based tin oxysulfides are reported. Single-crystal X-ray diffraction analysis reveals that both compound 1 [Sn](2)[Sn40O16S74](DMA)(4)(DEA)(10)(H+-DEA)(12)(H2O)(20) (DMA = dimethylamine, DEA = diethylamine) and compound 3 [Sn][Sn40O16S74](H+-DMA)(12)(DEA)(4)(H-2(2+)-DACH)(3)(H2O)(20)(DACH = 1,2-diaminocyclohexane) are built from oxygen-stuffed supertetrahedral T3-SnOS clusters with corner-sharing S2- and single Sn2+ ion as bridging linkers, and compound 2 [Sn40O16S73]- (DMA)(H+- TMA)(18)(H2O)(14) (TMA trimethylamine) is constructed by the interrupted supersupertetrahedral T3,2 clusters. Such variable and unique linkage modes are very useful for constructing other types of cluster-based crystalline open-framework chalcogenides. In addition, compound 2 is the first case that displays photoluminescence emission among T3-SnOS-based chalcogenides.

机译：这里报道了三种新型基于簇的氧氧硫化物。单晶X射线衍射分析显示化合物1 [Sn]（2）[Sn40O16S74]（DMA）（4）（DEA）（10）（10）（H 2 O）（20）（DMA）（DMA）（DMA） =二甲胺，DEA =二乙胺）和化合物3 [SN40O16S74]（H + -DMA）（12）（DEA）（4）（H-2（2 +） - 达氏）（3）（H2O）（20）（DACH = 1,2-二氨基环己烷）由具有拐角共享S2和单个SN2 +离子的氧填充的超级去型T3-SNOS簇构建，作为桥接接头，化合物2 [SN40O16S73] - （DMA）（H + - TMA）（ 18）（H 2 O）（14）（TMA三甲胺）由中断的超粒细胞T3,2簇构成。这种可变和独特的连杆模式对于构建其他类型的基于簇的晶体开放框架硫属化物是非常有用的。另外，化合物2是第一种显示基于T3-SNOS的硫族化合物之间的光致发光排放的情况。

著录项

来源
《Crystal growth & design》 |2018年第9期|共4页
作者
Lv Jing; Wang Wei; Zhang Li; Xue Chaozhuang; Hu Dandan; Wu Tao;
展开▼
作者单位

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Assembly of Oxygen-Stuffed Supertetrahedral T3-SnOS Clusters into Open Frameworks with Single Sn2+ Ion as Linker [J] . Lv Jing, Wang Wei, Zhang Li, Crystal growth & design . 2018,第9期

机译：将氧填充的超级去型T3-SNOS集团组装成具有单个SN2 +离子的开放式框架，作为接头
2. Co-assembly of a three-dimensional open framework sulfide with a novel linkage between an oxygen-encapsulated T3 cluster and a supertetrahedral T2 cluster [J] . Xiaohui Han, Zhenqing Wang, Dan Liu, Chemical Communications . 2014,第7期

机译：三维封装的框架硫化物的共组装，其中氧包裹的T3团簇和超四面体T2团簇之间具有新颖的连接
3. Supertetrahedral Cluster-Based In–Se Open Frameworks with Unique Polyselenide Ion as Linker [J] . Chaozhuang Xue, Jian Lin, Huajun Yang, Crystal growth & design . 2018,第5期

机译：基于SuperTeTraheDral群集的IN-SE开放式框架，具有独特的多糖烯IDE离子作为接头
4. Performance analysis of single and complete link during Agglomerative clustering of question papers by tagging the questions and trend analysis using single link [C] . Mishra Rasendu B., Modi Nilesh K., Shah Rushabh R. International Conference on Advanced Communication Control and Computing Technologies . 2014

机译：通过标记问题和使用单链接的趋势分析，在试卷的聚集聚类中对单个和完整链接的性能分析
5. A microsatellite markers-based framework linkage map of Vitis vinifera L. and genetic dissection of fruit cluster morphology traits. [D] . Riaz, Summaira. 2001

机译：基于微卫星标记的葡萄（Vitis vinifera L.）框架连接图和果实簇形态性状的遗传解剖。
6. Ethane diffusion in mixed linker zeolitic imidazolate framework-7-8 by pulsed field gradient NMR in combination with single crystal IR microscopy [O] . Samuel Berens, Christian Chmelik, Febrian Hillman, -1

机译：脉冲场梯度NMR结合单晶IR显微镜研究乙烷在混合接头沸石咪唑酸酯骨架-7-8中的扩散
7. Pushing up the size limit of chalcogenide supertetrahedral clusters: Two- and three-dimensional photoluminescent open frameworks from (Cu5In30S54)(13-) clusters [O] . Xianhui Bu(Univ Calif Santa Barbara Dept Chem), Nanfeng Zheng, 郑南峰, 2002

机译：推高硫族化物超四面体簇的尺寸限制：（Cu5In30S54）（13-）簇的二维和三维光致发光开放框架

Assembly of Oxygen-Stuffed Supertetrahedral T3-SnOS Clusters into Open Frameworks with Single Sn2+ Ion as Linker

摘要

著录项

相似文献

相关主题

期刊订阅