Porous Cyclotrimethylenetrinitramine with Reduced Sensitivity Prepared by a Solvation-Desolvation Method

Yan Mi; Liu Yu; Xu Jinjiang; Yang Liyuan; Zhang Lin; Nie Fude; Huang Shiliang

首页> 外文期刊>Crystal growth & design >Porous Cyclotrimethylenetrinitramine with Reduced Sensitivity Prepared by a Solvation-Desolvation Method

【24h】

Porous Cyclotrimethylenetrinitramine with Reduced Sensitivity Prepared by a Solvation-Desolvation Method

机译：多孔环二甲基四硝基丁胺具有通过溶剂化 - 降解方法制备的敏感性降低

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A crystal engineering strategy has been adopted to prepare a porous high explosive, cyclotrimethylenetrinitramine (RDX). Raw RDX was crystallized with TMS, CAM, and HMPT (TMS = tetramethylene sulfone, CAM = epsilon-caprolactone monomer, and HMPT = hexamethylphosphoramide), forming three solvates, RDX.TMS, RDX.CAM, and RDX.FIMPT, respectively. After desolvation by vacuum pyrolysis and antisolvent extraction, porous RDX containing micro- and nanoscale pores was successfully prepared. The porous RDX exhibits remarkably reduced impact, friction, and electrostatic spark sensitivity in comparison to raw RDX. A mechanism of the reduced sensitivity of porous RDX has also been proposed.

机译：采用了晶体工程策略来制备多孔高爆炸，环二甲基四缩四氢硝胺（RDX）。用TMS，CAM和HMPT（TMS =四亚甲基砜，CAM = epsilon-己内酯单体和HMPT =六甲基甲基磷酰胺）结晶，形成三种溶剂化物，RDX.TMS，RDX.CAM和RDX.fimpt。在真空热解和抗溶剂萃取后脱溶解后，成功制备了含有微型和纳米级孔的多孔RDx。与原始RDX相比，多孔RDX表现出显着降低的冲击，摩擦和静电火花敏感性。还提出了一种降低多孔RDX灵敏度的机制。

著录项

来源
《Crystal growth & design》 |2020年第8期|共8页
作者
Yan Mi; Liu Yu; Xu Jinjiang; Yang Liyuan; Zhang Lin; Nie Fude; Huang Shiliang;
展开▼
作者单位

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Porous Cyclotrimethylenetrinitramine with Reduced Sensitivity Prepared by a Solvation-Desolvation Method [J] . Yan Mi, Liu Yu, Xu Jinjiang, Crystal growth & design . 2020,第8期

机译：多孔环二甲基四硝基丁胺具有通过溶剂化 - 降解方法制备的敏感性降低
2. Hierarchical porous nitrogen doped reduced graphene oxide prepared by surface decoration-thermal treatment method as high-activity oxygen reduction reaction catalyst and high-performance supercapacitor electrodes [J] . Jia Zhijun, Wang Baoguo, Wang Yi, RSC Advances . 2016,第55期

机译：通过表面装饰 - 热处理方法制备的等级多孔氮掺杂石墨烯氧化物作为高活性氧还原反应催化剂和高性能超级电容电极
3. Hierarchical porous nitrogen doped reduced graphene oxide prepared by surface decoration–thermal treatment method as high-activity oxygen reduction reaction catalyst and high-performance supercapacitor electrodes [J] . Zhijun Jia, Baoguo Wang, Yi Wang, RSC Advances . 2016,第55期

机译：通过表面装饰 - 热处理方法制备的等级多孔氮掺杂石墨烯氧化物作为高活性氧还原反应催化剂和高性能超级电容电极
4. Porous carbon prepared by a template-like method using non-porous pumice mineral as template [C] . LIU Guiyang, LI Yannan, GUO Junming International Conference on Materials Science and Engineering Applications(ICMSEA) . 2011

机译：使用非多孔泵物矿物作为模板制备的多孔碳制备
5. Polymer composites and porous materials prepared by thermally induced phase separation and polymer-metal hybrid methods. [D] . Yoon, Joonsung. 2010

机译：通过热诱导相分离和聚合物-金属杂化方法制备的聚合物复合材料和多孔材料。
6. Preparation and Characterization of Cyclotrimethylenetrinitramine (RDX) with Reduced Sensitivity [O] . Yuqiao Wang, Xin Li, Shusen Chen, 2017

机译：灵敏度降低的环三亚甲基三硝胺（RDX）的制备和表征
7. Preparation and characterization of porous Si3N4 ceramics prepared by compression molding and slip casting methods [O] . Fangli Yu, Huanrui Wang, Yu Bai, 2010

机译：压缩成型和滑动铸造方法制备和表征多孔Si3N4陶瓷

Porous Cyclotrimethylenetrinitramine with Reduced Sensitivity Prepared by a Solvation-Desolvation Method

摘要

著录项

相似文献

相关主题

期刊订阅