Fluorescent Metal-Organic Framework Constructed from Semi-rigid Ligand for the Sensitive Sensing of 2,4,6-Trinitrophenol

Zhang Meng-Yun; Dai Ru-Dan; Li Bang-Jian; Hang Tian-Xiang; Xie Jia-Xin; Lu Jian; Zhu Xian-Dong

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Fluorescent Metal-Organic Framework Constructed from Semi-rigid Ligand for the Sensitive Sensing of 2,4,6-Trinitrophenol

机译：从半刚性配体构成的荧光金属 - 有机框架，用于2,4,6-三硝基苯酚的敏感感

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A Cd(II)-based metal-organic framework as fluorescent chemical sensor, formulated as {[Cd-3(bmipia)(2)]center dot 10DMF center dot 5H(2)O}(n) (FCS-2), was synthesized through a hydrothermal process and structurally characterized via X-ray crystallography. FCS-2 represented a new three-dimensional framework assembled from a semi -rigid aromatic carboxylate ligand and exhibited fascinating fluorescence due to the highly crystalline and ordered molecular structure. The emission of FCS-2 could be quenched, interestingly, by the presence of trace 2,4,6-trinitrophenol, which indicated that FCS-2 can be applied as a potentially sensitive fluorescent chemical sensor for the detection of nitroaromatic compounds.

机译：作为荧光化学传感器的CD（II）基于金属有机框架，配制为{[CD-3（BMIPIA）（2）]中心点10DMF中心点5H（2）O}（N）（FCS-2），通过水热过程合成，并通过X射线晶体学致在结构表征。 FCS-2表示从半纤维芳族羧酸盐配体组装的新三维框架，并且由于高结晶和有序的分子结构而表现出迷人的荧光。通过痕量2,4,6-三苯酚的存在，可以有趣的是，可以淬灭FCS-2的发射，这表明FCS-2可以作为潜在敏感的荧光化学传感器施加用于检测硝基芳族化合物。

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《Crystal growth & design》 |2020年第3期|共5页
作者
Zhang Meng-Yun; Dai Ru-Dan; Li Bang-Jian; Hang Tian-Xiang; Xie Jia-Xin; Lu Jian; Zhu Xian-Dong;
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作者单位

Anhui Polytech Univ Coll Biol &

Chem Engn Wuhu 241000 Peoples R China;

Anhui Polytech Univ Coll Biol &

Chem Engn Wuhu 241000 Peoples R China;

Anhui Polytech Univ Coll Biol &

Chem Engn Wuhu 241000 Peoples R China;

Anhui Polytech Univ Coll Biol &

Chem Engn Wuhu 241000 Peoples R China;

Anhui Polytech Univ Coll Biol &

Chem Engn Wuhu 241000 Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter Fuzhou 350002 Peoples R China;

Anhui Polytech Univ Coll Biol &

Chem Engn Wuhu 241000 Peoples R China;

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正文语种 eng
中图分类晶体学;
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1. Fluorescent Metal-Organic Framework Constructed from Semi-rigid Ligand for the Sensitive Sensing of 2,4,6-Trinitrophenol [J] . Zhang Meng-Yun, Dai Ru-Dan, Li Bang-Jian, Crystal growth & design . 2020,第3期

机译：从半刚性配体构成的荧光金属 - 有机框架，用于2,4,6-三硝基苯酚的敏感感
2. A multifunctional Zn(II)-based four-fold interpenetrated metal-organic framework for highly sensitive sensing 2,4,6-trinitrophenol (TNP), nitrofurazone (NFZ) and nitrofurantoin (NFT) [J] . Zhu Hai-Bin, Shen Yu, Fu Zhan-Zhao, Inorganic Chemistry Communications . 2019,第期

机译：基于多功能Zn（II）的四折服金属 - 有机骨架，用于高敏感感测2,4,6-三硝基苯酚（TNP），硝基脲（NFZ）和硝基脲（NFT）
3. Multifunctional luminescent Cd (II)-based metal-organic framework material for highly selective and sensitive sensing 2,4,6-trinitrophenol (TNP) and Fe3+ cation [J] . Hu Jinsong, Cheng Tingting, Dong Shengju, Microporous and mesoporous materials: The offical journal of the International Zeolite Association . 2018,第期

机译：基于多功能发光CD（II）的金属有机骨架材料，用于高选择性和敏感的感测2,4,6-三硝基苯酚（TNP）和Fe3 +阳离子
4. A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand [C] . Qing-Yu Ma, Rui-Fang Guan, Guo-Zhong Li, International Conference on Applied Mechanics and Materials . 2013

机译：由四面体硅芯配体构成的Mn（II）金属有机骨架
5. Dual-ligand Luminescent Metal-organic Frameworks Towards Environmental Remediation Efforts [D] . Rudd, Nathan D. 2018

机译：致力于环境修复的双配体发光金属有机框架
6. A fluorescent paramagnetic Mn metal–organic framework based on semi-rigid pyrene tetracarboxylic acid: sensing of solvent polarity and explosive nitroaromatics [O] . Alankriti Bajpai, Arindam Mukhopadhyay, Manchugondanahalli Shivakumar Krishna, 2015

机译：基于半刚性pyr四羧酸的顺磁性锰金属荧光骨架：感测溶剂极性和爆炸性硝基芳烃
7. 2Fold Interpenetrating Bifunctional Cd-MetalOrganic Frameworks: Highly Selective Adsorption for CO2 and Sensitive Luminescent Sensing of Nitro Aromatic 2,4,6-Trinitrophenol [O] . -1

机译：2倍互穿双官能CD-金属有机型框架：对硝基芳族2,4,6-三硝基苯酚的CO 2和敏感发光感测的高度选择性吸附

Fluorescent Metal-Organic Framework Constructed from Semi-rigid Ligand for the Sensitive Sensing of 2,4,6-Trinitrophenol

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