Spectroscopic Sensing of O-2-C2H2-C2H4 Flames for Diamond Growth Using Femtosecond Filamentation

Zhou Yun Shen; Wang Meng Meng; Lu Yao; Silvain Jean Francois; Lu Yong Feng

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Spectroscopic Sensing of O-2-C2H2-C2H4 Flames for Diamond Growth Using Femtosecond Filamentation

机译：使用Femtosecond丝状的O-2-C2H2-C2H4火焰的光谱检测

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The influence of the resonant vibrational excitation of the ethylene wagging mode (upsilon(7), 949.3 cm(-1)) on the combustion chemical vapor deposition of diamond was studied via femtosetorid laser-induced filamentation (FLIF) spectroscopy. The O-2-C2H2-C2H4 flame filaments were sampled within the diamond-formation zones to investigate the evolution of the diamond-formation-related species. In addition to higher diamond growth rates, increasing the incident laser power density led to the transitions of diamond crystal facets and quality as the results of competition between carbon-containing and OH-containing species. Evaluated using the C-2/OH number density ratio, {100}-faceted diamond crystals were obtained at the C-2/OH ratio of 110.00, while {111}-faceted diamond crystals were produced at the C-2/OH ratio of 133.34.

机译：通过Femtosetorid激光诱导的细丝（FLIF）光谱研究了乙烯淋巴模式（Upsilon（7），949.3cm（-1））对金刚石燃烧化学气相沉积的影响。在金刚石形成区内取样O-2-C2H2-C2H4火焰细丝，以研究与金刚石形成相关的物种的演变。除了较高的钻石生长速率之外，由于碳含量和含否的物种之间的竞争结果，引起了事件激光功率密度的增加导致了金刚石晶面和质量的转变。使用C-2 / OH数密度比评价，以110.00的C-2 / OH比获得{100} - 涤金金刚石晶体，而在C-2 / OH比下生产 133.34。

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《Crystal growth & design》 |2017年第6期|共7页
作者
Zhou Yun Shen; Wang Meng Meng; Lu Yao; Silvain Jean Francois; Lu Yong Feng;
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作者单位

Univ Nebraska Dept Elect &

Comp Engn Lincoln NE 68588 USA;

Univ Nebraska Dept Elect &

Comp Engn Lincoln NE 68588 USA;

Univ Nebraska Dept Elect &

Comp Engn Lincoln NE 68588 USA;

CNRS ICMCB Ave Docteur Albert Schweitzer F-33608 Pessac France;

Univ Nebraska Dept Elect &

Comp Engn Lincoln NE 68588 USA;

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正文语种 eng
中图分类晶体学;
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1. Spectroscopic Sensing of O-2-C2H2-C2H4 Flames for Diamond Growth Using Femtosecond Filamentation [J] . Zhou Yun Shen, Wang Meng Meng, Lu Yao, Crystal growth & design . 2017,第6期

机译：使用Femtosecond丝状的O-2-C2H2-C2H4火焰的光谱检测
2. 2–C₂H₂–C₂H₄ Flames for Diamond Growth Using Femtosecond Filamentation]]> [J] . Yun Shen Zhou, Meng Meng Wang, Yao Lu, JPC Bulletin on Iron & Steel . 2017,第6期

机译：<！[CDATA [o _{2 _{-c _{2 h _{2 -c _{2 h _{使用Femtosecond丝状钻石生长的4 火焰]]>}}}}}}
3. Simultaneous identification of multi-combustion-intermediates of alkanol-air flames by femtosecond filament excitation for combustion sensing [J] . Helong Li, Wei Chu, Huailiang Xu, Scientific reports. . 2016,第1期

机译：燃烧感应对飞秒丝激振动的烷醇 - 空气火焰多燃烧中间体的同时鉴定
4. Simulation of Substrate Temperature Distribution in Diamond Films Growth on Silicon Wafer by Hot Filament CVD [C] . T. Zhang, J.G. Zhang, B. Shen, Advances in materials manufacturing science and technology XIV . 2011

机译：热丝CVD法模拟硅片上金刚石薄膜生长中衬底温度分布
5. Nucleation and growth of combustion flame deposited diamond coatings on silicon nitride. [D] . Rozbicki, Robert T. 1999

机译：氮化硅上燃烧火焰沉积金刚石涂层的成核和生长。
6. Simultaneous identification of multi-combustion-intermediates of alkanol-air flames by femtosecond filament excitation for combustion sensing [O] . Helong Li, Wei Chu, Huailiang Xu, -1

机译：飞秒长丝激发同时识别烷醇-空气火焰的多种燃烧中间体
7. Spectroscopic Sensing of O2–C2H2–C2H4 Flames for Diamond Growth Using Femtosecond Filamentation [O] . Yun Shen Zhou, Meng Meng Wang, Yao Lu, 2017

机译：使用Femtosecond丝的O2-C2H2-C2H4火焰的光谱感测量
8. Influence of Filament Geometry on Hot Filament Growth of Diamond Films [R] . Farabaugh, E. N., Felfman, A., Robins, L. 1991

机译：长丝几何形状对金刚石薄膜热丝生长的影响

Spectroscopic Sensing of O-2-C2H2-C2H4 Flames for Diamond Growth Using Femtosecond Filamentation

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