Structural Diversity and Argentophilic Interactions in One-Dimensional Silver-Based Coordination Polymers

Lamming Glenn; Kolokotroni James; Harrison Thomas; Penfold Thomas J.; Clegg William; Waddell Paul G.; Probert Michael R.; Houlton Andrew

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Structural Diversity and Argentophilic Interactions in One-Dimensional Silver-Based Coordination Polymers

机译：一维银基配位聚合物的结构多样性和野营相互作用

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A series of new one-dimensional coordination polymer materials, based on Ag(I)-N bond formation, has been synthesized and structurally characterized by single crystal X-ray diffraction. Reactions between the poly-monodentate ligands based on (1E,1'E')-N,N'-(-bis(1-pyridin-3-yl)methanimine and Ag(I) salts give products that feature simple coordination chains or metallacyclic- and tape-based structures. For the simple chains these are as either isolated units, or assembled in dimeric and tetrameric arrangements through intermetallic, argentophilic interactions. However, crystal packing effects and solvent inclusion are found to readily disrupt this type of bonding. Density functional theory calculations provide an assessment of the bond order and the influence of anion binding on these interactions.

机译：基于Ag（I）-N键形成的一系列新的一维协调聚合物材料已经合成和结构特征，其特征在于单晶X射线衍射。基于（1E，1'E'） - N，N' - （ - BIS（1-吡啶-3-基）甲沙亚胺和Ag（I）盐的聚体配体与Ag（I）盐之间的反应提供了具有简单协调链的产品或金属谱和胶带基结构。对于简单的链，这些是作为分离的单元，或通过金属间化的野生菌相互作用组装在二聚体和四聚体布置中。然而，发现晶体填料效果和溶剂夹杂物容易破坏这种类型的粘合。密度函数理论计算提供了对债券秩序的评估和阴离子结合对这些相互作用的影响。

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《Crystal growth & design》 |2017年第11期|共11页
作者
Lamming Glenn; Kolokotroni James; Harrison Thomas; Penfold Thomas J.; Clegg William; Waddell Paul G.; Probert Michael R.; Houlton Andrew;
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作者单位

Newcastle Univ Sch Chem Chem Nanosci Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Chem Nanosci Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Chem Nanosci Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Crystallog Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Crystallog Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Crystallog Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

Newcastle Univ Sch Chem Chem Nanosci Lab Newcastle Upon Tyne NE1 7RU Tyne &

Wear England;

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正文语种 eng
中图分类晶体学;
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1. Structural Diversity and Argentophilic Interactions in One-Dimensional Silver-Based Coordination Polymers [J] . Lamming Glenn, Kolokotroni James, Harrison Thomas, Crystal growth & design . 2017,第11期

机译：一维银基配位聚合物的结构多样性和野营相互作用
2. Two Novel One-Dimensional alpha-Keggin-Based Coordination Polymers with Argentophilic {Ag-3}(3+)/{Ag-4}(4+) Clusters [J] . Dai LM, You WS, Wang EB, Crystal growth & design . 2009,第5期

机译：两种新型一维基于α-Keggin的配位聚合物，具有亲银的{Ag-3}（3 +）/ {Ag-4}（4+）团簇
3. Mononuclear, dinuclear, hexanuclear, and one-dimensional polymeric silver complexes having ligand-supported and unsupported argentophilic interactions stabilized by pincer-like 2,6-bis(5-pyrazolyl) pyridine ligands [J] . Zhou YB, Chen WZ, Wang DQ Dalton transactions: An international journal of inorganic chemistry . 2008,第11期

机译：单核，双核，六核和一维聚合物银配合物，具有由钳状2,6-双（5-吡唑基）吡啶配体稳定的配体支持和不支持的亲银相互作用
4. Design, Synthesis and Structural Diversity in Coordination Polymers [C] . Heba Abourahma, Gregory J. McManus, Brian Moulton, Metal- and Metalloid-Containing Macromolecules . 2003

机译：配位聚合物的设计，合成和结构多样性
5. Argentophilicity and structural diversity in double/multiple salts of silver acetylide/pseudohalide [D] . Wang, Quanming. 2001

机译：乙炔银/拟卤化物的双/多种盐的亲和性和结构多样性
6. One-Dimensional Mercury Halide Coordination Polymers Based on A Semi-Rigid N-Donor Ligand: Reversible Structural Transformation [O] . Pradhumna Mahat Chhetri, Xiang-Kai Yang, Chih-Tung Yang, 2019

机译：基于半刚性N配位体配体的一维卤化汞配位聚合物：可逆结构转变
7. Synthesis and Structural Characterization of a Series of One-Dimensional Heteronuclear Dirhodium-Silver Coordination Polymers [O] . Paula Cruz, Estefania Fernandez-Bartolome, Miguel Cortijo, 2019

机译：一系列一维异核矿泉银配位聚合物的合成与结构表征

Structural Diversity and Argentophilic Interactions in One-Dimensional Silver-Based Coordination Polymers

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