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首页> 外文期刊>ACS applied materials & interfaces >Dual Droplet Functionality: Phototaxis and Photopolymerization
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Dual Droplet Functionality: Phototaxis and Photopolymerization

机译:双液滴功能:光差和光聚合

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摘要

The use of phototaxis to move droplets in liquids offers the opportunity to emulate natural processes such as the controlled transport of materials in fluidic environments and to undertake chemistry at specific locations. We have developed a photoactive organic droplet, whose movement in aqueous solution is driven by a photoinitiator, as a result of a light-induced reaction within the droplet generating a Marangoni flow. The photoinitiator not only drives the droplet motion but can also be used to initiate polymerization following transfer of the droplet to a specific location and its merging with a monomer-containing droplet. The same light is used to control the transport of the droplet and the polymerization. The efficacy of this droplet transport and reactor system has been demonstrated by the site-specific underwater polymerization of N-isopropylacrylamide to repair a leaking vessel and the adhesion of two materials together.
机译:光图以在液体中移动液滴提供了机会,用于模拟流体环境中的物质的受控运输等自然过程,并在特定位置进行化学。 我们开发了一种光活性有机液滴,其在水溶液中的运动由光引发剂驱动,导致液滴内的光诱导反应产生Marangoni流程。 光引发剂不仅驱动液滴运动,而且还可用于在将液滴转移到特定位置后引发聚合,并用含单体液滴合并。 相同的光用于控制液滴和聚合的传输。 通过N-异丙基丙烯酰胺的位点特异性水下聚合来证明了该液滴输送和反应器系统的功效,以修复泄漏容器和两种材料的粘附。

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