Polymers of Intrinsic Microporosity Chemical Sorbents Utilizing Primary Amine Appendance Through Acid-Base and Hydrogen-Bonding Interactions

Sekizkardes Ali K.; Hammache Sonia; Hoffman James S.; Hopkinson David

首页> 外文期刊>ACS applied materials & interfaces >Polymers of Intrinsic Microporosity Chemical Sorbents Utilizing Primary Amine Appendance Through Acid-Base and Hydrogen-Bonding Interactions

【24h】

Polymers of Intrinsic Microporosity Chemical Sorbents Utilizing Primary Amine Appendance Through Acid-Base and Hydrogen-Bonding Interactions

机译：通过酸碱和氢键相互作用利用伯胺阑尾的内在微孔化学吸附剂的聚合物

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Here, we present novel chemical sorbents based on polymers with intrinsic microporosity (PIMs). For the first time, alkylamines were incorporated in PIMs through an acid-base interaction to create a chemisorbent. The amine-appended PIMs not only showed a nearly four-fold enhancement in CO2 loading capacity (36.4 cc/g at 0.15 bar and 298 K) and very high CO2/N-2 selectivity compared to neat PIM-1 but also proved to have stable performance when cycled between adsorption and desorption isotherms under both dry and humid conditions that are typical for postcombustion CO2 capture.

机译：在这里，我们基于具有内在微孔（PIMS）的聚合物的新型化学吸附剂。首先，通过酸碱相互作用将烷基胺掺入PIM中以产生化学吸附剂。胺附加的PIMS不仅在CO 2负载能力（36.4cc / g以0.15巴和298k时的36.4cc / g）和非常高的CO 2 / N-2选择性，而且还证明了在典型的后Combustion CO2捕获时，在干燥和潮湿条件下循环吸附和解吸等温线时稳定的性能。

著录项

来源
《ACS applied materials & interfaces》 |2019年第34期|共5页
作者
Sekizkardes Ali K.; Hammache Sonia; Hoffman James S.; Hopkinson David;
展开▼
作者单位

Natl Energy Technol Lab 626 Cochrans Mill Rd POB 10940 Pittsburgh PA 15236 USA;

Natl Energy Technol Lab 626 Cochrans Mill Rd POB 10940 Pittsburgh PA 15236 USA;

Natl Energy Technol Lab 626 Cochrans Mill Rd POB 10940 Pittsburgh PA 15236 USA;

Natl Energy Technol Lab 626 Cochrans Mill Rd POB 10940 Pittsburgh PA 15236 USA;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学工业;
关键词
PIM-1; porous organic polymers; amine impregnation; chemical sorbent; CO2 capture;

机译：PIM-1;多孔有机聚合物;胺浸渍;化学吸附剂;二氧化碳捕获;

相似文献

外文文献
中文文献
专利

1. Polymers of Intrinsic Microporosity Chemical Sorbents Utilizing Primary Amine Appendance Through Acid-Base and Hydrogen-Bonding Interactions [J] . Sekizkardes Ali K., Hammache Sonia, Hoffman James S., ACS applied materials & interfaces . 2019,第34期

机译：通过酸碱和氢键相互作用利用伯胺阑尾的内在微孔化学吸附剂的聚合物
2. Metastahle Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity [J] . Elena Madrid, Yuanyang Rong, Mariolino Carta Angewandte Chemie . 2014,第40期

机译：衍生自固有微孔性的胺基聚合物的Metastahle离子二极管
3. Selective dye adsorption by chemically-modified and thermally-treated polymers of intrinsic microporosity [J] . Satilmis Bekir, Budd Peter M. Journal of Colloid and Interface Science . 2017,第期

机译：通过化学改性和热处理聚合物的选择性染料吸附的内在微孔率
4. ACTIVATED POLYMER OF INTRINSIC MICROPOROSITY(PIM-1)WITH IMPROVED ELECTROCHEMICAL PERFORMANCE FOR LITHIUM-ION BATTERIES [C] . Yang Meng, Meng Qinghan, Cao Bing World Conference on Carbon . 2017

机译：具有改善的锂离子电池的内在微孔（PIM-1）的固有微孔（PIM-1）的活性聚合物
5. Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity. [D] . Lanni, Laura M. 2010

机译：硼酸酯连接的多孔材料的设计，合成，表征和评估：共价有机骨架和固有微孔性的聚合物。
6. Platinum Nanoparticle Inclusion into a Carbonized Polymer of Intrinsic Microporosity: Electrochemical Characteristics of a Catalyst for Electroless Hydrogen Peroxide Production [O] . Robert K. Adamik, Naiara Hernández-Ibáñez, Jesus Iniesta, 2018

机译：本征微孔碳化的聚合物中的铂纳米颗粒夹杂物：化学生产过氧化氢的催化剂的电化学特性
7. Enhancement of CO2 Affinity in a Polymer of Intrinsic Microporosity by Amine Modification [O] . Mason, Christopher, Maynard-Atem, Louise, Heard, Kane, 2014

机译：胺改性提高固有微孔聚合物中CO2的亲和力

Polymers of Intrinsic Microporosity Chemical Sorbents Utilizing Primary Amine Appendance Through Acid-Base and Hydrogen-Bonding Interactions

摘要

著录项

相似文献

相关主题

期刊订阅