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首页> 外文期刊>ACS applied materials & interfaces >Iron-Based Metal Organic Framework with Hydrophobic Quadrilateral Channels for Highly Selective Separation of Hexane Isomers
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Iron-Based Metal Organic Framework with Hydrophobic Quadrilateral Channels for Highly Selective Separation of Hexane Isomers

机译：具有疏水性四边形通道的铁基金属有机框架，用于高选择性分离己烷异构体

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摘要

A novel iron-based microporous metalorganic framework built of trinuclear iron clusters [Fe-3(mu(3)-O)(COO)(6)] and 2,2-bis(4-carboxyphenyl)-hexafluoropropane (6FDCA) has been prepared by solvothermal synthesis. It exhibits excellent chemical stability and strong hydrophobic character. More importantly, this material is capable of separating hexane isomers with good separation performance on the basis of a kinetically controlled process, making it a promising candidate for improving the research octane number of gasoline.
机译：由三核铁簇构建的新型铁基微孔金属有机框架[Fe-3（mu（3）-O）（COO）（6）]和2,2-双（4-羧基） - 氯丙烷（6FDCA）已经存在 通过溶剂热合成制备。 它表现出优异的化学稳定性和强烈的疏水性。 更重要的是，该材料能够在动力学控制的过程的基础上将具有良好分离性能的己烷异构体分离，使其成为改善研究辛烷值的汽油数量的有希望的候选者。

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  • 来源
  • 作者

    Lv Daofei; Wang Hao; Chen Yongwei; Xu Feng; Shi Renfeng; Liu Zewei; Wang Xinlong; Teat Simon J.; Xia Qibin; Li Zhong; Li Jing;

  • 作者单位

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    Rutgers State Univ Dept Chem &

    Chem Biol 610 Taylor Rd Piscataway NJ 08854 USA;

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    Northeast Normal Univ Coll Chem Changchun 130024 Jilin Peoples R China;

    Lawrence Berkeley Natl Lab Adv Light Source Berkeley CA 94720 USA;

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    South China Univ Technol Sch Chem &

    Chem Engn Guangzhou 510640 Guangdong Peoples R China;

    Rutgers State Univ Dept Chem &

    Chem Biol 610 Taylor Rd Piscataway NJ 08854 USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学工业;
  • 关键词

    iron-based metal-organic framework; chemical stability; hydrophobic character; hexane isomers; adsorptive separation;

    机译：铁基金属有机框架;化学稳定性;疏水性质;己烷异构体;吸附分离;

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