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首页> 外文期刊>ACS applied materials & interfaces >Rapidly Responsive and Flexible Chiral Nematic Cellulose Nanocrystal Composites as Multifunctional Rewritable Photonic Papers with Eco-Friendly Inks
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Rapidly Responsive and Flexible Chiral Nematic Cellulose Nanocrystal Composites as Multifunctional Rewritable Photonic Papers with Eco-Friendly Inks

机译:快速响应且柔性手性型纤维素纳米晶体复合材料,作为与生态型油墨的多功能可重写光子纸张

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摘要

Rapidly responsive and flexible photonic papers are manufactured by coassembly of cellulose nanocrystals (CNCs) and waterborne polyurethane (WPU) latex for fully taking advantage of the chiral nematic structure of CNCs and the flexibility of WPU elastomer. The resulting CNC/WPU composite papers exhibit not only tunable iridescent colors by adjusting the helical pitch size, but also instant optical responses to water and wet gas, ascribed to the easy chain movement of the elastomeric WPU that does not restrict the fast water absorption-induced swelling of CNCs. By choosing water or NaCl aqueous solutions as inks, the colorful patterns on the CNC/WPU photonic paper can be made temporary, durable, or even disguisable. In addition, the photonic paper is simultaneously rewritable for all these three types of patterns, and the disguisable patterns, which are invisible at normal times and show up under stimuli, exhibit a quick reveal conversion just by exhaling on the paper. The rewritability, rapid responsibility, easy fabrication, and the eco-friendly nature of the inks make the flexible photonic paper/ink combination highly promising in sensors, displays, and photonic circuits.
机译:快速响应且柔性光子纸由纤维素纳米晶(CNC)和水性聚氨酯(WPU)胶乳的合作制造,用于充分利用CNC的手性向志性结构和WPU弹性体的柔韧性。由此产生的CNC / WPU复合纸张不仅通过调节螺旋间距尺寸而且对水和湿气体的即时光学响应而展开,归因于不限制快速吸水 - 的易于限制诱导CNC的肿胀。通过选择水或NaCl水溶液作为墨水,CNC / WPU光子纸上的彩色图案可以暂时,耐用,甚至可挖掘。此外,光子纸同时为所有这三种类型的图案可重写,以及在正常时间下看不可见并在刺激下出现的可潜视图案,并且仅通过呼气在纸上展示快速揭示转换。可重款,快速责任,易于制造,以及墨水的环保性质使得灵活的光子纸/墨水组合在传感器,显示器和光子电路中具有高度承诺。

著录项

  • 来源
  • 作者单位

    Beijing Univ Chem Technol Coll Mat Sci &

    Engn Beijing Key Lab Adv Funct Polymer Composites Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol Coll Mat Sci &

    Engn Beijing Key Lab Adv Funct Polymer Composites Beijing 100029 Peoples R China;

    Univ Sci &

    Technol Beijing Sch Chem &

    Biol Engn Beijing 100083 Peoples R China;

    Beijing Univ Chem Technol Coll Mat Sci &

    Engn Beijing Key Lab Adv Funct Polymer Composites Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol Coll Mat Sci &

    Engn Beijing Key Lab Adv Funct Polymer Composites Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol Coll Mat Sci &

    Engn Beijing Key Lab Adv Funct Polymer Composites Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol Coll Mat Sci &

    Engn Beijing Key Lab Adv Funct Polymer Composites Beijing 100029 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学工业;
  • 关键词

    rewritable photonic paper; cellulose nanocrystals; stimuli response; disguisable pattern; chiral nematic composites;

    机译:可重写光子纸;纤维素纳米晶体;刺激反应;潜置模式;手性甲型复合材料;

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