Electrochemical Rejuvenation of Anodically Coloring Electrochromic Nickel Oxide Thin Films

Qu Hui-Ying; Primetzhofer Daniel; Arvizu Miguel A.; Qiu Zhen; Cindemir Umut; Granqvist Claes G.; Niklasson Gunnar A.

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Electrochemical Rejuvenation of Anodically Coloring Electrochromic Nickel Oxide Thin Films

机译：阳极着色电致变色氧化纤维薄膜的电化学再生

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Nickel oxide thin films are of major importance as anodically coloring components in electrochromic smart windows with applications in energy-efficient buildings. However, the optical performance of these films degrades upon extended electrochemical cycling, which has hampered their implementation. Here, we use a potentiostatic treatment to rejuvenate degraded nickel oxide thin films immersed in electrolytes of LiCLO4 in propylene carbonate. Time-of-flight elastic recoil detection analysis provided unambiguous evidence that both Lit ions and chlorine-based ions participate in the rejuvenation process. Our work provides new perspectives for developing ion-exchange-based devices embodying nickel oxide.

机译：氧化镍薄膜具有主要重要的是电致变色智能窗口中的阳极着色成分，具有节能建筑中的应用。然而，这些薄膜的光学性能在扩展电化学循环时劣化，这阻碍了它们的实现。在这里，我们使用电位处理将浸入LiClO 4的电解质中的降解的降解的镍氧化物薄膜在碳酸亚丙酯中。飞行时间的弹性反冲检测分析提供了明确的证据，即亮相和基于氯离子的含量参与了重新活化过程。我们的作品为开发体现氧化镍的离子交换的器件提供了新的视角。

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来源
《ACS applied materials & interfaces》 |2017年第49期|共5页
作者
Qu Hui-Ying; Primetzhofer Daniel; Arvizu Miguel A.; Qiu Zhen; Cindemir Umut; Granqvist Claes G.; Niklasson Gunnar A.;
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作者单位

Uppsala Univ Angstrom Lab Dept Engn Sci SE-75121 Uppsala Sweden;

Uppsala Univ Dept Phys &

Astron Angstrom Lab SE-75120 Uppsala Sweden;

Uppsala Univ Angstrom Lab Dept Engn Sci SE-75121 Uppsala Sweden;

Uppsala Univ Angstrom Lab Dept Engn Sci SE-75121 Uppsala Sweden;

Uppsala Univ Angstrom Lab Dept Engn Sci SE-75121 Uppsala Sweden;

Uppsala Univ Angstrom Lab Dept Engn Sci SE-75121 Uppsala Sweden;

Uppsala Univ Angstrom Lab Dept Engn Sci SE-75121 Uppsala Sweden;

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正文语种 eng
中图分类化学工业;
关键词
electrochromism; nickel oxide; thin film; electrochemical rejuvenation; ToF-ERDA;

机译：电致变色;氧化镍;薄膜;电化学复兴;TOF-ERDA;

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1. Electrochemical Rejuvenation of Anodically Coloring Electrochromic Nickel Oxide Thin Films [J] . Qu Hui-Ying, Primetzhofer Daniel, Arvizu Miguel A., ACS applied materials & interfaces . 2017,第49期

机译：阳极着色电致变色氧化纤维薄膜的电化学再生
2. Anodic Electrochromic Nickel Oxide Thin Films: Decay of Charge Density upon Extensive Electrochemical Cycling [J] . Wen Rui-Tao, Granqvist Claes G., Niklasson Gunnar A. ChemElectroChem . 2016,第2期

机译：阳极电致变色氧化镍薄膜：广泛的电化学循环时电荷密度的衰减
3. Anodic Electrochromic Nickel Oxide Thin Films: Decay of Charge Density upon Extensive Electrochemical Cycling (vol 3, pg 266, 2016) [J] . Wen R. -T., Granqvist C. G., Niklasson G. A. ChemElectroChem . 2016,第4期

机译：阳极电致变色氧化镍薄膜：广泛的电化学循环后电荷密度的衰减（第3卷，第266页，2016年）
4. Electrochromic and electrochemical properties of nickel oxide thin films prepared by a modified sol-gel method [C] . X. H. Xia, J. P. Tub, J. Zhang, International Conference on Multifunctional Materials and Structures . 2008

机译：通过改性溶胶 - 凝胶法制备的氧化镍薄膜的电致变色和电化学性能
5. Stress generation in thin anodic oxide films on titanium, aluminium and nickel. [D] . Nelson, John Christian. 1990

机译：在钛，铝和镍上的阳极氧化薄膜中产生应力。
6. Electrochemical Proton Intercalation in Vanadium Pentoxide Thin Films and its Electrochromic Behavior in the near‐IR Region [O] . Dr. Annika Buchheit, Britta Teßmer, Dr. Marina Muñoz‐Castro, 2021

机译：钒五氧化钒薄膜中的电化学质子嵌段及其在近红外地区的电致变色行为
7. Electrochemical Rejuvenation of Anodically Coloring Electrochromic Nickel Oxide Thin Films [O] . -1

机译：阳极着色电致变色氧化纤维薄膜的电化学恢复

Electrochemical Rejuvenation of Anodically Coloring Electrochromic Nickel Oxide Thin Films

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