One-Step Synthesis of Benzotetra- and Benzopentacyclic Compounds through Intramolecular [2+3] Photocycloaddition of Alkenes to Naphthalene

Hirofumi Mukae; Hajime Maeda; Kazuhiko Mizuno

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One-Step Synthesis of Benzotetra- and Benzopentacyclic Compounds through Intramolecular [2+3] Photocycloaddition of Alkenes to Naphthalene

机译：通过分子内的苯并异节和苯戊缩性化合物的一步合成[2 + 3]烯烃向萘的烯烃添加

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摘要

Photocycloaddition of unsaturated compounds to aromatic rings is a useful and convenient method for the construction of polycyclic compounds in organic synthesis.In particular,the inter- and intramolecular metaphotocycloaddition of alkenes to benzene rings has been extensively developed from the synthetic and mechanistic points of view in recent decades.

机译：不饱和化合物对芳环的光循环是一种有用且方便的方法，用于在有机合成中构建多环化合物。特别地，从综合和机械角度的观点中广泛地开发了烯烃与苯环的间分子内的中间体和分子内的中间体中央粘接。近几十年来。

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《Angewandte Chemie》 |2006年第39期|共3页
作者
Hirofumi Mukae; Hajime Maeda; Kazuhiko Mizuno;
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作者单位

Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University 1-1 Gakuen-cho Naka-ku Sakai Osaka 599-8531 (Japan);

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
cycloaddition; exciplexes; photochemistry; polycycles; triquinanes;

机译：环加成;Exciplecs;光化学;多环;Triquinanes;

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1. One-Step Synthesis of Benzotetra- and Benzopentacyclic Compounds through Intramolecular [2+3] Photocycloaddition of Alkenes to Naphthalene [J] . Hirofumi Mukae, Hajime Maeda, Kazuhiko Mizuno Angewandte Chemie . 2006,第39期

机译：通过分子内的苯并异节和苯戊缩性化合物的一步合成[2 + 3]烯烃向萘的烯烃添加
2. Synthesis of pentacyclic compounds via intramolecular [3+2] photocycloaddition of cycloalkene linked naphthalenes [J] . Maeda Hajime, Uesugi Tomoya, Fujimoto Yasufumi, Journal of Photochemistry and Photobiology, A. Chemistry . 2017,第期

机译：通过分子内的合成戊基化合物[3 + 2]环烷烃链环的萘萘
3. New photochemical rearrangements and extrusion reactions of aromatic compounds induced by an intramolecular [2+2] photocycloaddition between a naphthalene and a resorcinol moiety [J] . Hoffmann N. Tetrahedron . 2002,第39期

机译：萘与间苯二酚部分之间的分子内[2 + 2]光环加成反应诱导的芳族化合物的新光化学重排和挤出反应
4. Synthesis of Novel Heterotricyclic Compounds with Intramolecular 1,3- Dipolar Cycloaddition [C] . Cong Wang International symposium for Chinese organic chemists . 2000

机译：用分子内1,3-偶极环加入合成新型异质循环化合物
5. 1. Application of the intramolecular crossed [2 + 2] photocycloaddition/retro-Mannich/Mannich cascade of vinylogous imides toward the synthesis of a sarain A bicycle. 2. Studies directed toward the synthesis of nakadomarin A [D] . Fitzgerald, Mark E. 2008

机译：1.分子内交叉的[2 + 2]光环加成反应/乙烯基乙烯基酰亚胺的复古-曼尼希/曼尼希级联在萨兰A自行车合成中的应用。 2.研究nakadomarin A的合成
6. Diastereoselective Pyrrolidine Synthesis via Copper Promoted Intramolecular Aminooxygenation of Alkenes; Formal Synthesis of (+)-Monomorine [O] . Monissa C Paderes, Sherry R Chemler -1

机译：通过非对映铜合成吡咯烷促进烯的分子内aminooxygenation;的正式合成（+） - monomorine
7. Solid phase synthesis of isoxazole and isoxazoline-carboxamides via [2+3]-dipolar cycloaddition using resin-bound alkynes or alkenes [O] . Sureshbabu, Dadiboyena, Dadiboyena, Sureshbabu, Nefzi, Adel 2012

机译：使用树脂结合的炔烃或烯烃通过[2 + 3]-偶极环加成反应固相合成异恶唑和异恶唑啉甲酰胺
8. Direct Polynitroaliphatic Alcohol Addition to Alkenes. 2. One-Step Synthesis ofbeta-Substituted Polynitroalkyl Vinyl Ethers via an Alternative Transetherification Pathway [R] . Shackelford, S. A., McGuire, R. R., Cochoy, R. E. 1992

机译：直接多元脂族醇加成烯烃。 2.通过替代的Transetherification途径一步合成β取代的聚硝基烷基乙烯基醚

One-Step Synthesis of Benzotetra- and Benzopentacyclic Compounds through Intramolecular [2+3] Photocycloaddition of Alkenes to Naphthalene

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