Mixed-Valence Li/Fe-Based Metal-Organic Frameworks with Both Reversible Redox and Sorption Properties

Gérard Férey; Franck Millange; Mathieu Morcrette; Christian Serre; Marie-Liesse Doublet; Jean-Marc Grenèche; Jean-Marie Tarascon

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Mixed-Valence Li/Fe-Based Metal-Organic Frameworks with Both Reversible Redox and Sorption Properties

机译：具有可逆氧化还原和吸附特性的混合价锂/铁基金属有机骨架

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Metal-organic frameworks (MOFs) are promising multifunctional materials which can combine the properties of porous materials (catalysis, shape-selective absorption, gas storage, and purification) with those of dense inorganic phases (magnetism and optics). The performances of the new class of micro- and mesoporous metal-organic frameworks favorably compare with zeolites in terms of either CO2 capture, hydrogen sorption, or capabilities to host a wide variety of aqueous or nonaqueous solvent molecules for energy applications.

机译：金属有机骨架（MOF）是有前途的多功能材料，可以将多孔材料的特性（催化，择形吸收，气体存储和纯化）与致密的无机相（磁性和光学）相结合。新型的微孔和中孔金属有机骨架的性能在沸石的CO2捕集，氢吸附或承载多种水性或非水性溶剂分子的能力方面均可与沸石相媲美。

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来源
《Angewandte Chemie》 |2007年第18期|共5页
作者
Gérard Férey; Franck Millange; Mathieu Morcrette; Christian Serre; Marie-Liesse Doublet; Jean-Marc Grenèche; Jean-Marie Tarascon;
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正文语种 eng
中图分类应用化学;
关键词
lithium; microporous materials; Mossbauer spectroscopy; organic-inorganic hybrid composites; X-ray diffraction;

机译：锂;微孔材料;莫斯鲍尔光谱;有机-无机杂化复合材料;X射线衍射;

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专利

1. Mixed-Valence Li/Fe-Based Metal-Organic Frameworks with Both Reversible Redox and Sorption Properties [J] . Gérard Férey, Franck Millange, Mathieu Morcrette, Angewandte Chemie . 2007,第18期

机译：具有可逆氧化还原和吸附特性的混合价锂/铁基金属有机骨架
2. Post-synthetic reversible incorporation of organic linkers into porous metal-organic frameworks through single-crystal-to-single-crystal transformations and modification of gas-sorption properties [J] . Park H.J., Cheon Y.E., Suh M.P. Chemistry: A European journal . 2010,第38期

机译：合成后可逆地通过单晶到单晶转化和改变气体吸附性能将有机连接剂掺入多孔金属有机骨架中
3. The electronic structures and magnetic properties of mixed-valence Fe-based metal–organic VNU-15 frameworks: a theoretical study from linear response DFT+U calculations [J] . Diem Thi-Xuan Dang, Hieu Cao Dong, Yoshiyuki Kawazoe, RSC Advances . 2020,第57期

机译：混合价Fe基金属VNU-15框架的电子结构和磁性特性：线性响应DFT + U计算的理论研究
4. Proton-Coupled Reversible Redox Reaction of Zinc-Terephthalate Metal-Organic Framework [C] . Y. Hirai, S. Ueda, N. Nishiumi, International Conference on 4D Materials and Systems . 2019

机译：质子偶联锌 - 对苯二甲酸锌金属 - 有机骨架的可逆氧化还原反应
5. Design, synthesis, characterization, and sorption properties of metal-organic frameworks and polyhedra based on [iron(3)oxide(R dioxide)(6)L(3)](0/+) clusters. [D] . Sudik, Andrea C. 2005

机译：设计，合成，表征，和基于[铁（3）氧化物（R二氧化）（6）L（3）]（0 / +）簇的多面体的吸附性能。
6. Metal-Organic Frameworks to Metal/Metal Oxide Embedded Carbon Matrix: Synthesis Characterization and Gas Sorption Properties [O] . Jiun-Jen Chen, Ya-Ting Chen, Duraisamy Senthil Raja, 2015

机译：金属/金属氧化物嵌入的碳基体的金属有机骨架：合成表征和气体吸附性能
7. The electronic structures and magnetic properties of mixed-valence Fe-based metal–organic VNU-15 frameworks: a theoretical study from linear response DFT+U calculations [O] . Diem Thi-Xuan Dang, Hieu Cao Dong, Yoshiyuki Kawazoe, 2020

机译：混合价Fe基金属VNU-15框架的电子结构和磁性特性：线性响应DFT + U计算的理论研究

Mixed-Valence Li/Fe-Based Metal-Organic Frameworks with Both Reversible Redox and Sorption Properties

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