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Development of a Nitrazine Yellow-glycidyl methacrylate coating onto cotton fabric through thermal-induced radical polymerization reactions: a simple approach towards wearable pH sensors applications

机译:通过热诱导的自由基聚合反应在棉织物上甲基丙烯酸甲酯涂布甲基丙烯酸亚硝酸甲酯涂层:耐磨性pH传感器应用的简单方法

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摘要

In this paper, the bifunctional monomer glycidyl methacrylate (GMA) was employed in a simple two-step synthetic strategy with the aim of developing a Nitrazine Yellow-based pH-meter wearable sensor. The catalyzed epoxy ring-opening of GMA allowed the formation of a covalent bond with the sulfonate groups of the halochromic dyestuff, while potassium persulfate thermally initiated the radical grafting of the functionalized NY onto cellulose. Both reactions have been confirmed by Nuclear Magnetic Resonance Spectroscopy and by Infrared Spectroscopy, respectively. Furthermore, the morphology of the treated cotton samples was studied by means of Scanning Electron Microscopy. The pH-halochromic behaviour of the functionalized NY molecule was studied both in solution and onto the fabrics, by means of UV-Vis Spectroscopy, UV-Vis reflectance measurements and CIELAB colour changes. All experimental findings confirmed that the immobilized NY dyestuff still pertains consistent and typical halochromic properties in the pH range 6.0-7.0. The novel functional fabric developed in this work paves the way to non-disposable and reversible wearable pH sensors in smart textiles.
机译:本文将双功能单体甲基丙烯酸缩水甘油酯(GMA)用于一个简单的两步合成策略,旨在开发一种基于硝嗪黄的pH计可穿戴传感器。GMA的催化环氧开环允许与卤代铬染料的磺酸基形成共价键,而过硫酸钾热引发官能化NY自由基接枝到纤维素上。这两个反应分别通过核磁共振光谱和红外光谱得到了证实。此外,通过扫描电子显微镜对处理后的棉花样品的形态进行了研究。通过紫外-可见光谱、紫外-可见反射测量和CIELAB颜色变化,研究了功能化NY分子在溶液中和织物上的pH盐变色行为。所有实验结果证实,在pH值6.0-7.0范围内,固定化NY染料仍然具有一致和典型的卤代色素性质。本研究开发的新型功能织物为智能纺织品中的非一次性和可逆可穿戴pH传感器铺平了道路。

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