Predicting the performance of molecularly imprinted polymers: Selective extraction of caffeine by molecularly imprinted solid phase extraction

Keith Farrington; Edmond Magner; Fiona Regan

首页> 外文期刊>Analytica chimica acta >Predicting the performance of molecularly imprinted polymers: Selective extraction of caffeine by molecularly imprinted solid phase extraction

【24h】

Predicting the performance of molecularly imprinted polymers: Selective extraction of caffeine by molecularly imprinted solid phase extraction

机译：预测分子印迹聚合物的性能：通过分子印迹固相萃取选择性萃取咖啡因

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A rational design approach was taken to the planning and synthesis of a molecularly imprinted polymer capable of extracting caffeine(the template molecule)from a standard solution of caffeine and further from a food sample containing caffeine.Data from NMR titration experiments in conjunction with a molecular modelling approach was used in predicting the relative ratios of template to functional monomer and furthermore determined both the choice of solvent(porogen)and the amount used for the study.In addition the molecular modelling program yielded information regarding the thermodynamic stability of the pre-polymerisation complex.Post-polymerisation analysis of the polymer itself by analysis of the pore size distribution by BET yielded significant information regarding the nature of the size and distribution of the pores within the polymer matrix.Here is proposed a stepwise procedure for the development and testing of a molecularly imprinted polymer using a well-studied compound-caffeine as a model system.It is shown that both the physical characteristics of a molecularly imprinted polymer(MIP)and the analysis of the pre-polymerisation complex can yield vital information,which can predict how well a given MIP will perform.

机译：采用合理的设计方法来规划和合成能够从标准咖啡因溶液以及进一步从含有咖啡因的食物样品中提取咖啡因的分子印迹聚合物（模板分子）.NMR滴定实验结合分子的数据建模方法用于预测模板与功能性单体的相对比例，并同时确定溶剂（致孔剂）的选择和用于研究的量。此外，分子建模程序还提供了有关预聚合的热力学稳定性的信息通过BET的孔径分布分析对聚合物本身进行聚合后分析，得出有关聚合物基质中孔径大小和分布性质的重要信息。在此提出了逐步开发和测试聚合物的方法。使用经过充分研究的复合咖啡因的分子印迹聚合物结果表明，分子印迹聚合物（MIP）的物理特性和预聚合配合物的分析均可得出重要信息，这些信息可预测给定MIP的性能。

著录项

来源
《Analytica chimica acta》 |2006年第1期|共9页
作者
Keith Farrington; Edmond Magner; Fiona Regan;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类分析化学;
关键词
Molecular imprinting; Rational design; Pore size distribution; Molecular modelling; Solid phase extraction; Caffeine;

机译：分子印迹;理性设计;孔径分布;分子建模;固相萃取;咖啡因;

相似文献

外文文献
中文文献
专利

1. Predicting the performance of molecularly imprinted polymers: Selective extraction of caffeine by molecularly imprinted solid phase extraction [J] . Keith Farrington, Edmond Magner, Fiona Regan Analytica chimica acta . 2006,第1期

机译：预测分子印迹聚合物的性能：通过分子印迹固相萃取选择性萃取咖啡因
2. Preparation and evaluation of histamine imprinted polymer as a selective sorbent in molecularly imprinted solid-phase extraction coupled with high performance liquid chromatography analysis in canned fish. [J] . Sahebnasagh A., Karimi G., Mohajeri S. A. Food analytical methods . 2014,第1期

机译：组胺印迹聚合物作为分子印迹固相萃取中的选择性吸附剂的制备和评估，以及罐装鱼中的高效液相色谱分析。
3. Development of a highly sensitive and selective hyphenated technique (molecularly imprinted micro-solid phase extraction fiber-molecularly imprinted polymer fiber sensor) for ultratrace analysis of folic acid [J] . Bhim Bali Prasad, Mahavir Prasad Tiwari, Rashmi Madhuri Analytica chimica acta . 2010,第1期

机译：开发用于叶酸超痕量分析的高灵敏度和选择性联用技术（分子印迹微固相萃取纤维分子印迹聚合物纤维传感器）
4. Temperature in the Extraction Process: The Number of Cavities Created in Polymer Based on Molecularly Imprinted Polymer (MIP) Caffeine [C] . Idha Royani, Jumatul Rahmayani, Maimuna Padjadjaran International Physics Symposium . 2020

机译：提取过程中的温度：基于分子印迹聚合物（MIP）咖啡因的聚合物中产生的空腔数
5. Development of polypyrrole encapsulated nanomaterials in a syringe needle for automated molecularly imprinted solid phase extraction of ochratoxin A. [D] . Wei, Yun. 2007

机译：开发用于自动分子印迹固相萃取encapsulate曲霉毒素A的注射器针头中聚吡咯包裹的纳米材料。
6. A novel surface molecularly imprinted polymer as the solid-phase extraction adsorbent for the selective determination of ampicillin sodium in milk and blood samples [O] . Ningli Wu, Zhimin Luo, Yanhui Ge, 2016

机译：一种新型表面分子印迹聚合物作为固相萃取吸附剂用于选择性测定牛奶和血液样品中的氨苄西林钠
7. Solid-phase extraction using molecularly imprinted polymer for selective extraction of natural and syntetic estrogens from aqueous samples [O] . Lucci Paolo, Núñez Burcio Oscar, Galcerán Huguet M. Teresa 2016

机译：使用分子印迹聚合物固相萃取从水性样品中选择性萃取天然和合成雌激素

Predicting the performance of molecularly imprinted polymers: Selective extraction of caffeine by molecularly imprinted solid phase extraction

摘要

著录项

相似文献

相关主题

期刊订阅