Surface Patterning of Uniform 2D Platelet Block Comicelles via Coronal Chain Collapse

Charles N.  Jarrett-Wilkins; Samuel  Pearce; Liam R.  MacFarlane; Sean A.  Davis; Charl F. J.  Faul; Ian  Manners

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Surface Patterning of Uniform 2D Platelet Block Comicelles via Coronal Chain Collapse

机译：通过冠状链塌陷的均匀2D血小板块的表面图案化

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The formation of colloids with anisotropically patterned surfaces is of growing interest for the creation of hierarchical structures and the templating of nanoparticles. We have recently shown that well-defined two-dimensional platelets with low areal dispersities can be formed by the seeded growth of a blend of homopolymers and block copolymers. Herein we form rectangular platelets containing two block copolymers with different coronal chemistries. On addition of a solvent that is only able to solvate the corona of one block, we were able to form colloidally stable micelles with patterned surfaces via coronal collapse. Scanning transmission electron microscopy-energy-dispersive X-ray spectroscopy and atomic force microscopy were employed to provide information on the structure and size of the patches decorating the micelle surfaces.

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《ACS Macro Letters》 |2020年第11期|共7页
作者
Charles N. Jarrett-Wilkins; Samuel Pearce; Liam R. MacFarlane; Sean A. Davis; Charl F. J. Faul; Ian Manners;
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School of Chemistry University of Bristol Cantock’s Close;

School of Chemistry University of Bristol Cantock’s Close;

School of Chemistry University of Bristol Cantock’s Close;

School of Chemistry University of Bristol Cantock’s Close;

School of Chemistry University of Bristol Cantock’s Close;

School of Chemistry University of Bristol Cantock’s Close;

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正文语种 eng
中图分类有机化学;
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机译：具有三角形图案的穿孔板的塌陷表面，韧带效率在0.05和0.50之间

Surface Patterning of Uniform 2D Platelet Block Comicelles via Coronal Chain Collapse

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