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Microstructural, mechanical and pozzolanic characteristics of metakaolin-based geopolymer

机译:基于Metakaolin的地质聚合物的微观结构,机械和探测特征

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The use of cement contributes to global CO_2 emission and this leads to the depletion of ozone layer, causing global warming. The quest to reduce or eliminate this problem has resulted in the discovery of metakaolin- based geopolymer as an alternative to the use of cement in construction work. In this study, metakaolin obtained as a result of kaolin calcination from some deposits in Nigeria; Ogun (Imeko), Edo (Okpela), Ondo (Ifon) and Ekiti (Isan-Ekiti) were characterized and used to determine the compressive and flexural strength of metakaolin- based geopolymer concrete (Mk-GPC). Cubes of 150 × 150 × 150 mm were used for the compressive strength test and reinforced concrete beams of size 150 × 250 × 2160 mm were produced to test for flexural strength. A water- absorption test was also carried out on Mk-GPC and the effect of ball-milling was assessed on the strength properties. The results from the various tests showed that 800°C for 1 hour of calcination of kaolin gives best combination of performance properties due to the presence of amorphous silica in metakaolin. Mk-GPC gave higher compressive strength and at an early age than ordinary Portland cement (OPC) concrete. The water absorption capacities of Mk-GPC were higher than the control samples. In the flexural strength test, the reinforced beams failed in flexural-shear mode and the shear capacities at 28-, 56- and 90-day curing age of the beams were between 0.656 and 0.938 MPa for Mk-GPC beams and between 0.563 and 0.844 MPa for the control beams. The moment capacities for the beams were between 19.25 and 33.25 (×10~3 kgm~2/s~2) for Mk-GPC beams and were between 22.75 and 28.0 (×10~3 kgm~2/s~2) for the control beams. The study has revealed that metakaolin-based geopolymer can serve as an alternative to cement for sustainable construction in the Nigerian construction industry.
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