N General trends in concentration and temperature behavior of equivalent conductance of <Emphasis Type='Italic'>N,N</Emphasis>-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure
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General trends in concentration and temperature behavior of equivalent conductance of N,N-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure

机译：<重点型=“斜体”> N，N -dalylammonium聚合物水溶液的浓度和温度行为的浓度和温度行为的一般趋势：抗衡离子性质和胺结构的影响

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AbstractThe specific and equivalent conductivity of the diluted aqueous solutions of diallyammonium polyelectrolytes, initial monomers (N,N-diallylammonium trifluoroacetate,N,N-diallyl-N-methylammonium trifluoroacetate,N,N-diallyl-N,N-dimethylammonium chloride), and also potassium trifluoroacetate and trifluoroacetic acid solutions are studied. The limiting ionic mobility of diallylammonium cations and trifluoroacetate anion are found. The regularities of concentration changes in the equivalent conductance of polyelectolytes solutions are established. The degree of dissociation of diallyammonium polymers is shown to depend both on the counterion nature and on the amine structure.]]>
机译：摘要二烯丙基氨聚电解质、初始单体的稀释水溶液的比电导率和等效电导率（N，N，N，-三氟乙酸甲基铵、N，N-二烯丙基-N，N，N，以及三氟乙酸钾和三氟乙酸溶液。发现了二烯丙基铵阳离子和三氟乙酸阴离子的极限离子迁移率。建立了聚电解质溶液等效电导的浓度变化规律。二烯丙基铵聚合物的离解程度既取决于反离子性质，也取决于胺的结构]>

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  • 来源
    《Polymer science, Series C》 |2017年第1期|共8页
  • 作者

    L. M. Timofeeva; I. V. Balakaeva; A. S. Lileev; Yu. A. Simonova; A. K. Lyashchenko;

  • 作者单位

    Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences;

    Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

    Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences;

    Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences;

    Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

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  • 正文语种 eng
  • 中图分类 有机化学;
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