Strong circularly polarized luminescence of mixed lanthanide coordination polymers with control of 4f electronic structures

Islam Md Jahidul; Kitagawa Yuichi; Tsurui Makoto; Hasegawa Yasuchika

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Strong circularly polarized luminescence of mixed lanthanide coordination polymers with control of 4f electronic structures

机译：具有4F电子结构的混合镧系元配位聚合物的强圆偏振发光

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This paper reports chiral mixed Eu(iii)-Ln(iii) coordination polymers (Ln = Gd and Sm) with a high dissymmetry factor of circularly polarized luminescence (g(CPL) = 0.15) for the enhancement of the emission quantum yield (phi(tot) >= 50%), achieved via control of 4f electronic structures.

机译：本文报道了具有高不对称因子圆极化发光（g（CPL）=0.15）的手性混合铕（iii）-Ln（iii）配位聚合物（Ln=Gd和Sm），通过控制4f电子结构来提高发射量子产率（phi（tot）>=50%）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2021年第16期|共4页
作者
Islam Md Jahidul; Kitagawa Yuichi; Tsurui Makoto; Hasegawa Yasuchika;
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Hokkaido Univ Inst Chem React Design &

Discovery WPI ICReDD Kita 21 Nishi 10 Sapporo Hokkaido 0010021 Japan;

Hokkaido Univ Inst Chem React Design &

Discovery WPI ICReDD Kita 21 Nishi 10 Sapporo Hokkaido 0010021 Japan;

Hokkaido Univ Grad Sch Chem Sci &

Engn Kita 13 Nishi 8 Sapporo Hokkaido 0608628 Japan;

Hokkaido Univ Inst Chem React Design &

Discovery WPI ICReDD Kita 21 Nishi 10 Sapporo Hokkaido 0010021 Japan;

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正文语种 eng
中图分类化学;无机化学;
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1. Synthesis and X-ray crystal structures of a series of 3d–4f lanthanide complexes: lanthanide(III)–copper(II) coordination polymers with 2,5-pyridinedicarboxylic acid ligand [J] . Zhuo Wang, Yong Heng Xing, Chun Guang Wang, Transition Metal Chemistry . 2009,第6期

机译：一系列3d–4f镧系元素配合物的合成和X射线晶体结构：具有2,5-吡啶二羧酸配体的镧系元素（III）-铜（II）配位聚合物
2. Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning [J] . Min Zeng, Ang Ren, Wubin Wu, Chemical science . 2020,第34期

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3. Brilliant Sm, Eu, Tb, and Dy chiral lanthanide complexes with strong circularly polarized luminescence [J] . Petoud S, Muller G, Moore EG, Journal of the American Chemical Society . 2007,第1期

机译：具有强圆偏振发光的出色Sm，Eu，Tb和Dy手性镧系元素络合物
4. Structures and luminescence of mixed lanthanide(Tb3+,Eu3+)coordination CMC and HPCMC [C] . Weipeng Liang, Jun Ye, Jian Xiong 第五届制浆造纸新技术国际研讨会（ISETPP）暨第三届国际造纸与环境学术大会（IPEC）论文集 . 2016

机译：镧系元素（Tb3 +，Eu3 +）配位CMC和HPCMC的结构和发光
5. Synthesis, characterization and luminescence of lanthanide (cerium, lanthanum, europium, gadolinium, ytterbium and yttrium) Schiff-base coordination monomers, polymers and polyelectrollytes. [D] . Chen, Huiyong. 1995

机译：镧系元素（铈，镧，euro，g 、,和钇）的合成，表征和发光。席夫碱配位单体，聚合物和聚电解质。
6. Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning [O] . Min Zeng, Ang Ren, Wubin Wu, 2020

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8. Reliable Electronic Structure Calculations for Heavy Element Chemistry: Molecules Containing Actinides, Lanthanides, and Transition Metals Relativistic Pseudopotentionals in Accurate ab Initio Molecular Electronic Structure Calculations [R] . Marino, M. M. 2005

机译：可靠的电子结构计算重元素化学：含有act系元素，镧系元素和过渡金属的分子相对论赝势在精确的ab initio分子电子结构计算中的应用

Strong circularly polarized luminescence of mixed lanthanide coordination polymers with control of 4f electronic structures

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