Embedded homogeneous ultra-fine Pd nanoparticles within MOF ultra-thin nanosheets for heterogeneous catalysis

Guo Taolian; Mo Kaili; Zhang Nannan; Xiao Lipengcheng; Liu Wenlong; Wen Lili

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Embedded homogeneous ultra-fine Pd nanoparticles within MOF ultra-thin nanosheets for heterogeneous catalysis

机译：MOF超薄纳米片内的嵌入均匀超细PD纳米粒子用于异质催化

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Metal nanoparticle-incorporated metal-organic framework (MOF) nanosheets can integrate their respective merits to have important applications in heterogeneous catalysis. Herein, we report the loading of ultra-fine Pd nanoparticles within ultra-thin nanosheets NMOF-Ni through an in situ reduction strategy under mild conditions. Owing to the synergetic effects of ultra-small Pd NPs and the intrinsic characteristics of two-dimensional supports, the obtained Pd@NMOF-Ni showed high catalytic activity and size-selectivity in olefin hydrogenation with easy recovery. Meanwhile, Pd@NMOF-Ni is also highly active in the catalytic reduction of aqueous 4-nitrophenol to 4-aminophenol.

机译：金属纳米粒子结合金属有机骨架（MOF）纳米片可以综合各自的优点，在多相催化中有重要的应用。在此，我们报告了在温和条件下，通过原位还原策略将超细钯纳米颗粒装入镍纳米薄膜NMOF中。由于超小型钯纳米颗粒的协同效应和二维载体的固有特性，获得了Pd@NMOF-镍在烯烃加氢反应中表现出较高的催化活性和粒度选择性，且易于回收。同时Pd@NMOF-镍在4-硝基苯酚水溶液催化还原为4-氨基苯酚的过程中也具有很高的活性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2021年第5期|共6页
作者
Guo Taolian; Mo Kaili; Zhang Nannan; Xiao Lipengcheng; Liu Wenlong; Wen Lili;
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Cent China Normal Univ Coll Chem Minist Educ Key Lab Pesticide &

Chem Biol Wuhan 430079 Peoples R China;

Cent China Normal Univ Coll Chem Minist Educ Key Lab Pesticide &

Chem Biol Wuhan 430079 Peoples R China;

Cent China Normal Univ Coll Chem Minist Educ Key Lab Pesticide &

Chem Biol Wuhan 430079 Peoples R China;

Cent China Normal Univ Coll Chem Minist Educ Key Lab Pesticide &

Chem Biol Wuhan 430079 Peoples R China;

Yangzhou Univ Coll Chem &

Chem Engn Yangzhou 225002 Jiangsu Peoples R China;

Cent China Normal Univ Coll Chem Minist Educ Key Lab Pesticide &

Chem Biol Wuhan 430079 Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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3. Au Core-Pd Shell Bimetallic Nanoparticles Immobilized within Hyper-Cross-Linked Polystyrene for Mechanistic Study of Suzuki Cross-Coupling: Homogeneous or Heterogeneous Catalysis? [J] . Nemygina Nadezhda A., Nikoshvili Linda Zh., Tiamina Irina Yu., Organic process research & development . 2018,第12期

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4. High Loading of Pd Nanoparticles by Interior Functionalization of MOFs for Heterogeneous Catalysis [J] . Gole Bappaditya, Sanyal Udishnu, Banerjee Rahul, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第5期

机译：通过MOF内部功能化高负载钯纳米颗粒的非均相催化
5. High Loading of Pd Nanoparticles by Interior Functionalization of MOFs for Heterogeneous Catalysis [J] . Gole Bappaditya, Sanyal Udishnu, Banerjee Rahul, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第5期

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机译：均相和多相催化关系国际研讨会（第13期）。简介（2008）

Embedded homogeneous ultra-fine Pd nanoparticles within MOF ultra-thin nanosheets for heterogeneous catalysis

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