Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

Alexander F Schmidt; Anna A. Kurokhtina; Elizaveta V. Larina

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Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

机译：差异选择性测量和竞争反应方法作为复杂催化反应的机械研究的有效手段

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In most kinetic investigations of catalytic reactions, catalytic activity is a traditionally measured kinetic parameter. However, differential selectivity measurements have many advantages for mechanistic studies. This Perspective gives an overview of the basic principles and practices of mechanistic studies based on differential selectivity measurements, including the use of artificially created competitive reactions.

机译：在大多数对催化反应的动力学研究中，催化活性是传统测量的动力学参数。但是，差异选择性测量在机械研究方面具有许多优势。这种观点概述了基于差异选择性测量的机械研究的基本原理和实践，包括使用人为创建的竞争反应。

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来源
《Catalysis science & technology》 |2014年第10期|3439-3457|共19页
作者
Alexander F Schmidt; Anna A. Kurokhtina; Elizaveta V. Larina;
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作者单位

Department of Chemistry of the Irkutsk State University, K. Marx Str., 1, 664003, Irkutsk, Russia.;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
Catalysis; Dens; REACTIONDifferentialselectivityKinetic parameters;

机译：催化;dens;反应差异性运动参数;

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Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

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