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Enzymatic synthesis of sugar fatty acid esters in ionic liquids

机译:离子液体中糖脂肪酸酯的酶促合成

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摘要

Sugar fatty acid esters are nonionic biosurfactants widely used in food, cosmetic and pharmaceutical industries. Ionic liquids (ILs) have shown great potential as an alternative reaction medium to conventional organic solvents for their enzymatic synthesis, promoting a significant enhancement in sugar solubility, enzymatic reactivity and regioselectivity. In this perspective, we summarize the advances in the use of ILs as a solvent for sugar dissolution and lipase-catalyzed sugar ester synthesis, review the recent achievements in designing enzyme-compatible ILs for the synthesis, and discuss the challenges that the research on this topic is facing. Among the advanced ILs, deep eutectic solvents (DESs) merit a serious consideration as a potential reaction medium for this application.
机译:糖脂肪酸酯是广泛用于食品,化妆品和制药行业的非离子生物表面活性剂。 离子液体(ILS)表现出巨大的潜力,作为传统有机溶剂的替代反应培养基,用于其酶促合成,从而促进了糖溶解度,酶促反应性和区域选择性的显着增强。 从这个角度来看,我们总结了使用IL作为糖溶解和脂肪酶催化糖酯的综合的溶剂的进步,回顾了在设计酶兼容ILS合成的最新成就,并讨论有关此挑战的挑战 主题面临。 在晚期IL中,深色溶剂(DESS)值得认真考虑作为该应用的潜在反应介质。

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