Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides

Wei Huang; Baixiang Li; Youhong Wang

首页> 外文期刊>Catalysis science & technology >Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides

【24h】

Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides

机译：半二苯二世2-（1-（Arylimino）乙基）喹啉-8-酸性氯化物的合成，表征和乙烯（共同）聚合行为

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The series of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate dichlorides, Cp'TiCl2L (Cp' = η~5-C5H5 or η~5-C5Me5, L = 2-(1-(2,6-R~1-4-R~2-phenylimino)ethyl)quinolin-8-olate), was synthesized via the stoichiometric reaction of Cp'TiCl3 with the corresponding potassium salt, viz. 2-(1-(2,6-R~1-4-R~2-phenylimino)ethyl)quinolin-8-olate. All compounds were characterized by elemental analysis, ~1H and ~(13)C NMR spectroscopy. The molecular structures of complexes C2 and C4 were determined by single-crystal X-ray diffraction. When activated with methylaluminoxane (MAO), all half-titanocene pre-catalysts exhibited high activities for ethylene polymerization and co-polymerization with α-olefins or norbornene.

机译：一系列的半苯二世2-（1-（Arylimino）乙基）喹啉-8-酸性二氯化物，cp'ticl2l（Cp'= η〜5-C5H5或η〜5-C5me5，L = 2-（1-（1-（1-（1-（1） 2,6-r〜1-4-r〜2-苯基氨基）乙基）喹啉-8-酸酯通过CP'TICL3与相应的钾盐的化学计量反应合成。 2-（1-（1-（2,6-R〜1-4-R〜2-苯基胺）乙基）喹啉-8-酸酯。所有化合物均通过元素分析（〜1H和〜（13）C NMR光谱法）表征。通过单晶X射线衍射确定复合物C2和C4的分子结构。当用甲基氨基氧烷（MAO）激活时，所有半二苯二苯甲酸前催化剂均表现出较高的活性，可与α-烯烃或诺伯烯烯共聚合和共聚合。

著录项

来源
《Catalysis science & technology》 |2011年第7期|1208-1215|共8页
作者
Wei Huang; Baixiang Li; Youhong Wang;
展开▼
作者单位

Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.;

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
ethylene; dichlorides; ELEMENTAL ANALYSISpotassium saltsynthesisseries (mathematics)chloridescoperniciummolecular structure;

机译：乙烯;二氯化剂;元素分析盐盐盐盐（数学）;

相似文献

外文文献
中文文献
专利

1. HALF-TITANOCENE CHLORIDES 2-（BENZIMIDAZOL-2-YL）QUINOLIN-8- OLATES： SYNTHESIS, CHARACTERIZATION AND ETHYLENE （CO-）POLYMERIZATION BEHAVIOR [J] . Wen-juan Zhang, Wei Huang, Tong-ling Liang, 高分子科学：英文版 . 2013,第004期
2. Synthesis, structural characterization and solubility of 2-(1-substituted- 1,11-undecylidene)-5-arylimino-△~3-1,3, 4-thiadiazolines [J] . Shu Hui Jin, Xiao Mei Liang, Xu Yang, 中国化学快报（英文版） . 2009,第11期
3. 2-(l-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolylcobaltdichloride: Synthesis and polyethylene wax formation [J] . Wen-Hua Sun, Shaoliang Kong, Wenbin Chai Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2012,第null期

机译：2-（1-（Arylimino）ethyl）-8-arylimino-5,6,7-trihydroquinolylcobaltdichloride：合成和聚乙烯蜡的形成
4. 2-(l-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolylcobaltdichloride: Synthesis and polyethylene wax formation [J] . Wen-Hua Sun, Shaoliang Kong, Wenbin Chai Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2012,第null期

机译：2-（1-（Arylimino）ethyl）-8-arylimino-5,6,7-trihydroquinolylcobaltdichloride：合成和聚乙烯蜡的形成
5. 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline iron(II) chloride complexes: Synthesis, characterization, and ethylene polymerization behavior [J] . Zhang W., Chai W., Sun W.-H., Organometallics . 2012,第14期

机译：2-（1-（Arylimino）ethyl）-8-arilimino-5,6,7-trihydroquinoline氯化铁（II）配合物：合成，表征和乙烯聚合行为
6. 1-(2-Carboxyethyl)-5-ethyl-2-methylpyridinium chloride [O] . V. Sabari, G. Kalaiselvi, S. Balasubramanian, 2012

机译：1-（2-咔氧基乙基）-5-乙基-2-甲基chloride氯化chloride
7. Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of epsilon-caprolactone [O] . Pan X.B., Liu A., Yao L.H., 2014

机译：synthesis, characterization of hetero-bimetallic complex and application in the polymerization of epsilon-caprolactone

Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides

摘要

著录项

相似文献

相关主题

期刊订阅