Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power

Biriukov Klim O.; Vinogradov Mikhail M.; Afanasyev Oleg IVasilyev Dmitry V.Tsygankov Alexey A.Godovikova MariaNelyubina Yulia VLoginov Dmitry A.Chusov Denis

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Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power

机译：碳monoxide-driven锇催化还原氨基化收获WGSR权力

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Herein, we present the first example of Os-catalyzed efficient reductive amination under water-gas shift reaction conditions. The developed catalytic systems are formed in situ in aqueous solutions, employ as small as 0.0625 mol% osmium and are capable of delivering reductive amination products for a broad range of aliphatic and aromatic carbonyl compounds and amines. The scope of the reaction, active catalytic systems, possible limitations of the method and DFT-supported mechanistic considerations are discussed in detail in the manuscript.

机译：在此,我们的第一个例子Os-catalyzed高效下还原胺化水气交换反应条件。开发催化系统原位形成水解决方案,采用小0.0625摩尔%锇和能够提供还原为广泛的脂肪族胺产品和芳香羰基化合物和胺。反应的范围,积极催化系统,可能的方法和局限性DFT-supported机械的考虑在手稿中详细讨论。

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《Catalysis science & technology》 |2021年第14期|4922-4930|共9页
作者
Biriukov Klim O.; Vinogradov Mikhail M.; Afanasyev Oleg IVasilyev Dmitry V.Tsygankov Alexey A.Godovikova MariaNelyubina Yulia VLoginov Dmitry A.Chusov Denis;
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作者单位

Russian Acad Sci INEOS RAS, AN Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow, Russia;

Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Egerlandstr 3, D-91058 Erlangen, Germany;

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正文语种英语
中图分类汉语教学;
关键词
Water gas shift reaction; Amination; Manuscriptscarbonyl compoundsShift reactionosmiumaqueous solutionsReducing Agents;

机译：水煤气转移反应,胺化作用;ManuscriptscarbonylcompoundsShift reactionosmiumaqueoussolutionsReducing代理;

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Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power

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