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Localized catalysis driven by the induction heating of magnetic nanoparticles

机译:本地化催化由感应磁性纳米颗粒的加热

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摘要

Controlling temperature with high spatial resolution has been a challenge and the bottleneck for advancing scientific discoveries at the micro-scale level. Herein, we exploit the heat generated from magnetic nanoparticles when placed in an alternating magnetic field to drive catalytic chemical reactions. A catalytic microstructure was assembled using a positively charged polyelectrolyte in the presence of negatively charged magnetic and gold nanoparticles. As a proof of concept, we monitored the conversion of resazurin into the fluorescent resorufin in solution and when confined in small hydrogels. In both cases, we demonstrate the possibility to drive chemical reactions using the locally generated heat from magnetic nanoparticles. This might prove an effective strategy for energy efficient catalysis.
机译:控制温度高的空间和分辨率一直是一个挑战推进科学发现的瓶颈在微观层次上的水平。热量从磁纳米粒子生成的放置在一个交变磁场来驱动催化的化学反应。微观结构是使用积极的组装被聚电解质的存在带负电荷的磁性和黄金纳米粒子。监控刃天青到的转换在溶液中荧光resorufin当关在小的水凝胶。证明可能驱动化学反应使用本地生成的热量磁性纳米粒子。有效的节能策略催化。

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