Coordination chemistry and catalysis with secondary phosphine oxides

Gallen Albert; Riera Antoni; Verdaguer XavierGrabulosa Arnald

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Coordination chemistry and catalysis with secondary phosphine oxides

机译：配位化学和催化作用二次膦氧化物

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Secondary phosphine oxides present tautomeric equilibrium between the pentavalent oxide form (SPO) and the trivalent phosphinous acid (PA). This dichotomy is the origin of the rich coordination chemistry of this class of compounds. As the pentavalent oxide form usually predominates, SPOs are air-stable but at the same time metal coordination can shift the tautomerism towards the PA form, making the ligand act as an ordinary trivalent phosphine. For this reason, this class of ligands has found application in numerous homogeneously catalysed reactions, including some enantioselective transformations. This review aims to give an up-to-date account on the synthesis, coordination chemistry and homogeneous catalysis of SPOs.

机译：互变异构的二次膦氧化物存在五价的氧化物形式之间的平衡(热点)和三价phosphinous酸(PA)。这种二分法是富人的起源这类配位化学化合物。主导,检测air-stable但相同时间金属协调可以转移互变现象对巴勒斯坦权力机构形式,使配体作为普通的三价磷化氢。这类配体发现应用程序中许多对均匀催化反应,包括一些拆分转换。本文的目的是给出一个最新的账户的合成、配位化学和均相催化进行比较。

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《Catalysis science & technology》 |2019年第20期|5504-5561|共58页
作者
Gallen Albert; Riera Antoni; Verdaguer XavierGrabulosa Arnald;
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作者单位

Barcelona Inst Sci & Technol, Inst Res Biomed IRB Barcelona, Baldiri & Reixac 10, Barcelona 08028, Spain;

Univ Barcelona, Seccio Quim Inorgan, Dept Quim Inorgan & Organ, Marti & Franques 1-11, E-08028 Barcelona, Spain;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
PHOSPHINE OXIDES; Catalysis; PhosphinesChemistryTautomerismoxides;

机译：磷化氢氧化物,催化;PhosphinesChemistryTaut;

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Coordination chemistry and catalysis with secondary phosphine oxides

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