alpha-Ferrous oxalate dihydrate: an Fe-based one-dimensional metal organic framework with extraordinary photocatalytic and Fenton activities

Li Kai; Liang Yujun; Yang JianYang GuiXu RuiXie Xianjun

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alpha-Ferrous oxalate dihydrate: an Fe-based one-dimensional metal organic framework with extraordinary photocatalytic and Fenton activities

机译：二水草酸alpha-Ferrous: Fe-based一维金属有机框架非凡的光催化和芬顿活动

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An Fe(II)-based metal organic framework, alpha-ferrous oxalate dihydrate (alpha-FOD), with remarkable n-type semiconductor characteristics has been successfully prepared for use as a bifunctional catalyst in both photocatalysis and Fenton oxidation. The photoreduction of Cr(VI) into Cr(III) under visible light irradiation (5 W LED lamp) revealed the superior photocatalytic activity of alpha-FOD, where 50 mL of 100 mg.L-1 Cr(VI) was reduced within 6 minutes. Moreover, alpha-FOD exhibited significant Fenton oxidation activity in degrading organic compounds in presence of H2O2 in the dark.

机译：一个铁(II)的金属有机框架,alpha-ferrous草酸二水合物(alpha-FOD)显著的n型半导体特性已经成功地准备使用作为一个吗在光催化和双功能催化剂芬顿氧化。为铬(III)可见光照射下(5 WLED灯)揭示了优越的光催化alpha-FOD活动,50毫升100毫克。铬(VI)是减少在6分钟。alpha-FOD方面表现出显著的芬顿氧化活动在降解有机化合物在黑暗中过氧化氢的存在。

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来源
《Catalysis science & technology》 |2018年第23期|6057-6061|共5页
作者
Li Kai; Liang Yujun; Yang JianYang GuiXu RuiXie Xianjun;
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作者单位

China Univ Geosci, State Key Lab Biogeol & Environm Geol, Wuhan 430074, Hubei, Peoples R China;

China Univ Geosci, Engn Res Ctr Nanogeomat, Minist Educ, Wuhan 430074, Hubei, Peoples R China;

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正文语种英语
中图分类汉语教学;
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Lamps; n-type semiconductors; dual catalysthydrogen peroxidemetal organic frameworkorganic compoundsoxalatesCr3+LED lampsPhotocatalystsactivity;

机译：灯;n型半导体;双重catalysthydrogenperoxidemetal有机frameworkorganiccompoundsoxalatesCr3 +领导lampsPhotocatalystsactivity;

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alpha-Ferrous oxalate dihydrate: an Fe-based one-dimensional metal organic framework with extraordinary photocatalytic and Fenton activities

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