Room temperature silylation of alcohols catalyzed by metal organic frameworks

Dhakshinamoorthy Amarajothi; Santiago-Portillo Andrea; Concepcion PatriciaHerance Jose R.Navalon SergioAlvaro MercedesGarcia Hermenegildo

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Room temperature silylation of alcohols catalyzed by metal organic frameworks

机译：醇催化室温甲硅烷基化通过金属有机框架

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摘要

The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH)(BDC) is stable under the reaction conditions as evidenced by powder XRD and can be reused with minimal activity decrease.

机译：商业Al (OH) (BDC) (BDC:1,金属有机4-benzenedicarboxylic酸)框架(Basolite A100)是合适的异构的甲硅烷基化的催化剂苄基的和脂肪族醇类在甲苯hexamethyldisilazane房间温度。反应条件就是明证粉末x射线衍射可以重用,以最少的活动减少。

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来源
《Catalysis science & technology》 |2017年第12期|2445-2449|共5页
作者
Dhakshinamoorthy Amarajothi; Santiago-Portillo Andrea; Concepcion PatriciaHerance Jose R.Navalon SergioAlvaro MercedesGarcia Hermenegildo;
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作者单位

Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India;

Vall dHebron Res Inst, Grp Imagen Med Mol, CIBBIM Nanomed, Pg Vall dHebron 119-129, Barcelona, Spain;

Univ Politecn Valencia, Inst Univ Tecnol Quim CSIC UPV, Ave Naranjos S-N, E-46022 Valencia, Spain;

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正文语种英语
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关键词
Aliphatic alcohols; hexamethylsilazane; Room temperaturesilylationmetal organic frameworkEnvironmental TemperaturePOLYMERISATION CONDITIONSFrameworksToluene;

机译：temperaturesilylationmetal有机frameworkEnvironmental TemperaturePOLYMERISATIONCONDITIONSFrameworksToluene;

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Room temperature silylation of alcohols catalyzed by metal organic frameworks

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