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首页> 外文期刊>Boletin de la Sociedad Espanola de Ceramica y Vidrio >Electric conductivity of Aurivillius ceramic materials of composition Pb_xBi_4Ti_(3+x)O_(12+3x), x=0,1,2 y 3
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Electric conductivity of Aurivillius ceramic materials of composition Pb_xBi_4Ti_(3+x)O_(12+3x), x=0,1,2 y 3

机译:组成为Pb_xBi_4Ti_(3 + x)O_(12 + 3x),x = 0,1,2 y 3的Aurivillius陶瓷材料的电导率

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摘要

The ac electric conductivity of both textured and non textured Aurivillius ferroelectric ceramics Pb_xBi_4Ti_(3+x)O_(12+3x), where x = 0,1,2 and 3, has been studied by impedance measurements. The electrical conductivity decreases approximately one order of magnitude with the incorporation of a mol of lead titanate into the bismuth titanate structure. The anisotropy of the conductivity is kept between the ab plane and the c axis. The response seems to be related to the number of oxygen vacancies present in the crystalline structure of the materials, as well as to the aspect ratio of the grains. The activation energy values of the electrical conduction process are presented for both the ferroelectric and paraelectric phases.
机译:已经通过阻抗测量研究了纹理化和非纹理化Aurivillius铁电陶瓷Pb_xBi_4Ti_(3 + x)O_(12 + 3x)的交流电导率,其中x = 0,1,2和3。通过将一摩尔钛酸铅掺入钛酸铋结构中,电导率降低约一个数量级。电导率的各向异性保持在ab平面和c轴之间。该响应似乎与材料的晶体结构中存在的氧空位的数量以及晶粒的长径比有关。给出了铁电相和顺电相的导电过程的活化能值。

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