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Recent advances in spectroelectrochemistry

机译:最近的进步光谱电化学法

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摘要

The integration of two quite different techniques, conventional electrochemistry and spectroscopy, into spectroelectrochemistry (SEC) provides a complete description of chemically driven electron transfer processes and redox events for different kinds of molecules and nanoparticles. SEC possesses interdisciplinary advantages and can further expand the scopes in the fields of analysis and other applications, emphasizing the hot issues of analytical chemistry, materials science, biophysics, chemical biology, and so on. Considering the past and future development of SEC, a review on the recent progress of SEC is presented and selected examples involving surface-enhanced Raman scattering (SERS), ultraviolet-visible (UV-Vis), near-infrared (NIR), Fourier transform infrared (FTIR), fluorescence, as well as other SEC are summarized to fully demonstrate these techniques. In addition, the optically transparent electrodes and SEC cell design, and the typical applications of SEC in mechanism study, electrochromic device fabrication, sensing and protein study are fully introduced. Finally, the key issues, future perspectives and trends in the development of SEC are also discussed.
机译:两种截然不同的技术的集成,传统的电化学和光谱,光谱电化学法(SEC)提供了一个的完整描述化学驱动的电子转移过程和氧化还原事件不同种类的分子和纳米颗粒。SEC具有跨学科的优势和能进一步扩大领域的范围分析和其他应用程序,强调分析化学、材料的热点问题科学,生物物理学,化学生物学,等等。考虑到过去和未来发展证券交易委员会,审查的最新进展交会选定的例子包括表面增强拉曼散射(ser),可见-紫外可见),近红外(NIR),傅里叶变换红外(FTIR),荧光,以及其他证券交易委员会进行了总结充分证明这些技术。此外,光学透明电极SEC单元设计,典型的应用程序美国证券交易委员会的机制研究中,电致变色的设备制造、检测和蛋白质研究完全介绍了。视角和证交会的发展趋势进行了讨论。

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