首页> 外文期刊>Archives of Metallurgy and Materials >MECHANISM OF THE ANODIC DISSOLUTION OF Fe70-Cu16-Co10 ALLOY ORIGINATED FROM REDUCED COPPER CONVERTER SLAG IN AMMONIACAL SOLUTIONS. RECOVERY OF COPPER AND COBALT
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MECHANISM OF THE ANODIC DISSOLUTION OF Fe70-Cu16-Co10 ALLOY ORIGINATED FROM REDUCED COPPER CONVERTER SLAG IN AMMONIACAL SOLUTIONS. RECOVERY OF COPPER AND COBALT

机译:氨溶液中还原的铜转化渣产生的Fe70-Cu16-Co10合金的阳极溶解机理。铜和钴的回收

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摘要

Industrial copper converter slag was subjected to reduction roasting, in which Fe70-Cu16-Co10 alloy was obtained. This alloy was dissolved anodically in an ammonia-ammonium chloride solution. This resulted in the separation of the metals, wherein iron remained in the slime, while copper and cobalt were components of slime, electrolyte and cathodic deposit. A mechanism of the anodic dissolution process was developed. The alloy was a three-phase system and did not dissolve uniformly. A series of secondary processes took place in the system: precipitation of iron compounds and adsorption of copper and cobalt ions on the iron precipitates. A hydrometallurgical method of copper and cobalt recovery was developed.
机译:对工业铜转炉炉渣进行还原焙烧,得到Fe70-Cu16-Co10合金。将该合金阳极溶解在氨-氯化铵溶液中。这导致了金属的分离,其中铁保留在煤泥中,而铜和钴是煤泥,电解质和阴极沉积物的成分。研究了阳极溶解过程的机理。该合金是三相体系,不能均匀溶解。系统中发生了一系列次要过程:铁化合物的沉淀以及铁沉淀物上铜和钴离子的吸附。开发了一种湿法冶金法回收铜和钴的方法。

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