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Visible and near-ultraviolet absorption spectrum of liquid water

机译:液态水的可见和近紫外吸收光谱

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The optical absorption of pure liquid water in the 300-700-nm region has been measured by use of a long (1.5-m) path-length cell. The absorption spectrum coincides well with the edge of previous data in the 200-320-nm region and provides reliable data in the 320-420-nm region that has until now been a region of considerable unreliability. The data obtained for the 420-700-nm region agree quite well with the means Of the existing literature in that well-studied region. The absorptions in the 550-700-nm region show evidence for the overtones and combination tones of the well-known OH stretching frequency at 3500 cm~(-1).
机译:通过使用长(1.5-m)光程池测量了300-700 nm区域中纯净液态水的光吸收。吸收光谱与200-320 nm区域中先前数据的边缘非常吻合,并在320-420 nm区域中提供可靠的数据,而该区域迄今为止一直是相当不可靠的区域。在420-700 nm区域获得的数据与该研究好的区域中现有文献的方法非常吻合。 550-700nm区域的吸收显示了众所周知的OH拉伸频率在3500 cm〜(-1)时的泛音和组合音。

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