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Spectroscopic properties of Nd↑(3+) and pr↑(3+) in gallate glasses with low phonon energies

机译:低声子能的镓酸盐玻璃中Nd↑(3+)和pr↑(3+)的光谱性质

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Absorption and fluorescence spectra of Nd↑(3-) were measured m potassium tantalum gallate, lead bismuth gallate (PBG), fluorozirconate (ZBLAN), and Ge-Ga-S glasses. A Judd-Ofelt analysis was performed to determine the spontaneous emission probability and stimulated emission cross section of the ↑(4)F↓(2/3) → ↑(4)I↓(11/2) transition of Nd↑(3-). Raman spectra were studied to clarify the maximum phonon energies of the glasses. The fluorescence of the ↑(1)G↓(4)→↑(3)H↓(5) transition of P↑(3-) in a dehydrated PBG glass was observed for the first time to our knowledge. The PBG glass has a higher quantum efficiency than that of ZBLAN glass based on the Judd-Ofelt analysis. #1997 Optical Society of America
机译:在钽酸镓钽,铅酸铋铋(PBG),氟锆酸盐(ZBLAN)和Ge-Ga-S玻璃中测量Nd↑(3-)的吸收和荧光光谱。进行Judd-Ofelt分析以确定Nd↑(3-)的↑(4)F↓(2/3)→↑(4)I↓(11/2)转变的自发发射概率和受激发射截面)。研究了拉曼光谱,以澄清玻璃的最大声子能量。据我们所知,这是在脱水的PBG玻璃中首次观察到P↑(3-)的↑(1)G↓(4)→↑(3)H↓(5)跃迁的荧光。根据Judd-Ofelt分析,PBG玻璃比ZBLAN玻璃具有更高的量子效率。 #1997美国眼镜学会

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