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首页> 外文期刊>Archives of Environmental Contamination and Toxicology >Endocrine-Disrupting Compounds in Reclaimed Water and Residential Ponds and Exposure Potential for Dislodgeable Residues in Turf Irrigated With Reclaimed Water
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Endocrine-Disrupting Compounds in Reclaimed Water and Residential Ponds and Exposure Potential for Dislodgeable Residues in Turf Irrigated With Reclaimed Water

机译:再生水和住宅池塘中破坏内分泌的化合物以及再生水灌溉草皮中可清除残留物的暴露潜力

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摘要

Endocrine-disrupting chemicals (EDCs) occur in reclaimed water (RW), which may serve as an exposure source for humans. The presence of EDCs in RW used to irrigate turf and in nearby water-retention ponds was determined. In addition, the total dislodgeable mass of each EDC was determined after irrigation (using RW) to simulate exposure of a 3-year-child playing in turf grass recently irrigated with RW. Five EDCs (estrone, 17 beta-estradiol, 17 alpha-ethynylestradiol, bisphenol A, and 4-n-nonylphenol) were quantified in 28 samples of RWs (wastewater-treatment plant effluents) and 88 samples from residential surface water-retention ponds. St. Augustine variety of turf grass was irrigated with spiked RW to study dislodgement of the five EDCs overtime using a drag-sled method. Grass clippings were analyzed to relate masses of EDC on grass with masses dislodged. EDCs were detected in both RW and ponds at ng/L concentrations. Maximum EDC masses were dislodged immediately after irrigation. Dislodged masses of estrone and 17 beta-estradiol are two separate EDCs, 17 beta-estradiol and 17 alpha-ethynylestradiol decreased rapidly and were lower than detection limits 4 h after application. Dislodged bisphenol-A and nonylphenol decreased more slowly but were not detected 6 h after application. Avoiding contact with recently irrigated turf grass should decrease the risks of exposure to these EDCs.
机译:破坏内分泌的化学物质(EDC)出现在再生水(RW)中,可作为人类的暴露源。确定了用于灌溉草皮的RW和附近保水池中是否存在EDC。此外,灌溉后(使用RW)确定每个EDC的总可移动质量,以模拟最近用RW灌溉的3岁儿童在草皮上玩耍的情况。在28个RW(废水处理厂废水)样品和88个居住地表蓄水池样品中,对5种EDC(雌酮,17种β-雌二醇,17种α-乙炔基雌二醇,双酚A和4-正壬基酚)进行了定量。使用钉状RW灌溉圣奥古斯丁草皮草,研究了使用拖拉式雪橇方法加班后五个EDC的位移。分析了草屑,以将草上EDC的质量与脱落的质量相关联。在RW和池塘中均以ng / L浓度检测到EDC。冲洗后立即清除最大EDC重量。雌酮和17β-雌二醇的脱落量是两个单独的EDC,应用后4 h,17β-雌二醇和17α-乙炔基雌二醇迅速下降并且低于检出限。施用后6小时,移出的双酚A和壬基酚的下降较慢,但未检测到。避免与最近灌溉过的草皮接触,应减少接触这些EDC的风险。

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