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首页> 外文期刊>Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry >Electrochemical Behaviour of Quinaldic Acid at Dropping Mercury Electrode and Hanging Mercury Drop Electrode
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Electrochemical Behaviour of Quinaldic Acid at Dropping Mercury Electrode and Hanging Mercury Drop Electrode

机译:喹啉酸在滴汞电极和悬滴汞电极上的电化学行为

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摘要

The polarographic and cyclic voltammetric studies of quinaldic acid are made at dropping mercury electrode and hanging mercury drop electrode in buffer solutions of various pH values.The polarographic half wave potentials and cyclic voltammetric peak potentials are shifted to more negative values,whilst limiting currents and peak currents are found to decrease with the increase in the pH of the buffer solution.The polarographic wave and cyclic voltammetric peaks are found to be irreversible and diffusion controlled.The values of kinetic parameters are computed using Meites-Israel method.
机译:在不同pH值的缓冲溶液中滴汞电极和悬挂汞滴电极上进行喹啉酸的极谱和循环伏安研究,极谱半波电位和循环伏安峰电位移至更大的负值,同时出现极限电流和峰值。随着缓冲溶液pH值的增加,电流减小。极谱波和循环伏安峰不可逆且受扩散控制。动力学参数的值使用Meites-Israel方法计算。

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