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Low-Temperature Oxidation Properties of Carboxyl in Coal Based on Model Compound of Spontaneous Combustion of Coal

机译:基于煤自燃模型化合物的煤中羧基的低温氧化特性

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摘要

According to coal spontaneous combustion theory and coal molecular structure, benzoic acid was adopted as model compound of coal spontaneous combustion by temperature programming to study oxidation reaction under different temperatures (293-423 K). Besides, the generated oxidation products under different reaction conditions were analyzed qualitatively and quantitatively via GC-MS. Reaction temperature and reaction time are the major factors which affect low-temperature oxidation of benzoic acid. This study has provided reference for low-temperature oxidation properties of sole activity structure in coal molecular structure from chemical perspective.
机译:根据煤自燃理论和煤分子结构,通过温度程序设计采用苯甲酸作为煤自燃的模型化合物,研究了在不同温度(293-423 K)下的氧化反应。此外,通过GC-MS对不同反应条件下产生的氧化产物进行了定性和定量分析。反应温度和反应时间是影响苯甲酸低温氧化的主要因素。该研究从化学角度为煤分子结构中单一活性结构的低温氧化性能提供了参考。

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