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首页> 外文期刊>Inorganic Chemistry Communications >Unexpected fragmentation of the Fe_3(CO)_9(#mu#_3-Se)(#mu#_3-AsCH_3)cluster core in the reaction with CpCo(CO)_2: synthesis and structure of Fe_3(CO)_6(#mu#_3-Se)(#mu#_3-Se)(#mu#-AsCH_3{CpFe(CO)_2})_2(#mu#-CO)
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Unexpected fragmentation of the Fe_3(CO)_9(#mu#_3-Se)(#mu#_3-AsCH_3)cluster core in the reaction with CpCo(CO)_2: synthesis and structure of Fe_3(CO)_6(#mu#_3-Se)(#mu#_3-Se)(#mu#-AsCH_3{CpFe(CO)_2})_2(#mu#-CO)

机译:Fe_3(CO)_9(#mu#_3-Se)(#mu#_3-AsCH_3)团簇核在与CpCo(CO)_2反应中发生意外碎裂:Fe_3(CO)_6(#mu# _3-Se)(#mu#_3-Se)(#mu#-AsCH_3 {CpFe(CO)_2})_ 2(#mu#-CO)

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摘要

The [Fe_3(CO)_6(#mu#_3-Se)(#mu#_3-Se)(#mu#-AsCH_3{CpFe(CO)_2})_2(#mu#-CO)](Cp=#mu#~5-C_5H_5) cluster has been obtained by the reaction of [Fe_3(CO)_9(#mu#_3-Se)(#mu#_3-Se)(#mu#-AsCH_3)]with[CpFe(CO)_2)]. Its crystal and molecular structures have been determined by X-ray analysis.
机译:[Fe_3(CO)_6(#mu#_3-Se)(#mu#_3-Se)(#mu#-AsCH_3 {CpFe(CO)_2})_ 2(#mu#-CO)](Cp =# mu [〜5-C_5H_5)簇是通过[Fe_3(CO)_9(#mu#_3-Se)(#mu#_3-Se)(#mu#-AsCH_3)]与[CpFe(CO) )_2)]。它的晶体和分子结构已经通过X射线分析确定。

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