Highly proton-conductive copper coordination polymer, H_2dtoaCu (H_2dtoa = dithiooxamide anion)

Hiroshi Kitagawa; Yuki Nagao; Musashi Fujishima; Ryuichi Ikeda; Seiichi Kanda

首页> 外文期刊>Inorganic Chemistry Communications >Highly proton-conductive copper coordination polymer, H_2dtoaCu (H_2dtoa = dithiooxamide anion)

【24h】

Highly proton-conductive copper coordination polymer, H_2dtoaCu (H_2dtoa = dithiooxamide anion)

机译：高质子传导性铜配位聚合物H_2dtoaCu（H_2dtoa =二硫代草酰胺阴离子）

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Room-temperature proton conductivity, coordination geometry, and pore-diameter distribution of the title Cu(II) coordination polymer have been investigated by AC conductivity, EXAFS, and N_2 adsorption isotherm measurements. The AC proton conductivity (sigma_p) obtained from Cole-Cole plot analysis under relative humidity of 75% and 300 K exhibits a considerable high value of 10~(-6) S cm~(-1) as a room-temperature sigma_p. The mechaism of proton conduction seems to be similar to that of a proton-exchange membrane, Nafion, which contains much cluster of water molecules in the porous space of the polymer. The present Cu coordination polymer was revealed to possess porous spaace of about 6 A, which includes much water molecules more than 10H_2O per unit cell. The dimeric Cu(II) square-planar coordination geometry was confirmed by EXAFS analysis using synchrotron radiation source at SPring-8.

机译：通过交流电导率，EXAFS和N_2吸附等温线研究了标题Cu（II）配位聚合物的室温质子电导率，配位几何结构和孔径分布。通过Cole-Cole图分析获得的交流质子电导率（sigma_p）在相对湿度为75％和300 K的情况下表现出相当高的10〜（-6）S cm〜（-1）室温值。质子传导的机制似乎类似于质子交换膜Nafion的机制，Nafion在聚合物的多孔空间中包含许多水分子簇。揭示了本发明的Cu配位聚合物具有约6A的多孔空间，其中每单位细胞包含大于10H_2O的许多水分子。通过使用SPring-8同步辐射源进行EXAFS分析，确认了二聚体Cu（II）的方形平面配位几何。

著录项

来源
《Inorganic Chemistry Communications》 |2003年第4期|共3页
作者
Hiroshi Kitagawa; Yuki Nagao; Musashi Fujishima; Ryuichi Ikeda; Seiichi Kanda;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
solid state ionics; proton conduction; hydrogen storage; protone-exchange membrane;

机译：固态离子质子传导储氢质子交换膜;

相似文献

外文文献
中文文献
专利

1. Highly proton-conductive copper coordination polymer, H_2dtoaCu (H_2dtoa = dithiooxamide anion) [J] . Hiroshi Kitagawa, Yuki Nagao, Musashi Fujishima, Inorganic Chemistry Communications . 2003,第4期

机译：高质子传导性铜配位聚合物H_2dtoaCu（H_2dtoa =二硫代草酰胺阴离子）
2. A new proton-conductive copper coordination polymer, (HOC3H6)(2)dtoaCu (dtoa = dithiooxamide) [J] . Nagao Y., Ikeda R., Iijima K., Synthetic Metals . 2003,第1a3期

机译：一种新型的质子传导性铜配位聚合物（HOC3H6）（2）dtoaCu（dtoa =二硫代草酰胺）
3. A new proton-conductive copper coordination polymer, (HOC_3H_6)_2dtoaCu (dtoa = dithiooxamide) [J] . Y. Nagao, R. Ikeda, K. Iijima Synthetic Metals . 2003,第4期

机译：一种新型的质子传导性铜配位聚合物（HOC_3H_6）_2dtoaCu（dtoa =二硫代草酰胺）
4. Humidity-Assisted Highly Selective Ammonia Sensors Based on Nonconjugated Proton-Conductive Polymers [C] . Hongran Zhao, Lichao Liu, Jianxun Dai, Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

机译：基于非共轭质子导电聚合物的湿度辅助高选择性氨传感器
5. Tetradipicolyamine-substituted resorc[4]arene cavitands: I. Anion binding and transition metal assembled coordination cages and nanoarchitectures. II. Polymer inclusion membranes applied to anion separations. [D] . Gardner, Joseph S. 2005

机译：Tetradipicolyamine取代的间苯二酚[4]芳烃空洞：I.阴离子结合和过渡金属组装的配位笼和纳米结构。二。适用于阴离子分离的聚合物包合物膜。
6. Progress on highly proton-conductive polymer thin films with organized structure and molecularly oriented structure [O] . Yuki Nagao 2020

机译：具有组织结构和分子取向结构的高质子传导性聚合物薄膜的研究进展
7. Anion-Induced Structural Diversity of Zn and Cd Coordination Polymers Based on Bis-9,10-(pyridine-4-yl)-anthracene, Their Luminescent Properties, and Highly Efficient Sensing of Nitro Derivatives and Herbicides [O] . Serhii I. Vasylevskyi, Dario M. Bassani, Katharina M. Fromm 2019

机译：基于BIS-9,10-（吡啶-4-基） - 蒽，其发光性能，对硝基衍生物和除草剂的高效感测Zn和Cd配位聚合物的阴离子和Cd配位聚合物的结构多样性

Highly proton-conductive copper coordination polymer, H_2dtoaCu (H_2dtoa = dithiooxamide anion)

摘要

著录项

相似文献

相关主题

期刊订阅