First hexanuclear manganese(II) mu_6-Cl centered carboxylate anion:Synthesis,structure and magnetic properties

Mikhail A.Kiskin; Grygory G.Aleksandrov; Vladimir N.Ikorskii

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First hexanuclear manganese(II) mu_6-Cl centered carboxylate anion:Synthesis,structure and magnetic properties

机译：第一六核锰（II）mu_6-Cl中心羧酸根阴离子：合成，结构和磁性

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Reaction of manganese(II) polymer [Mn5Cl(OH)(Piv)_8(MeCN)(HPiv)(H2O)]_n (1,HPiv is pivalic acid) and 2-benzoylpyridine (L) in MeCN produces the ionic complex [Mn3(Piv)5L2(MeCN)]~+[Mn6Cl(Piv)i2]~-o MeCN (3) containing the unusual hexanuclear {Mn6(u6-Cl)} anion.An analogous anion was also observed in the complex [Mn6Cl(Piv)12]_(NEt_4)~+o 5MeCN (4) prepared by the reaction of the polymer [Mn(Piv)2(EtOH)]" (2) with NEt4Cl in MeCN.Complexes 3 and 4 were characterized by the X-ray diffraction and magnetic susceptibility.

机译：锰（II）聚合物[Mn5Cl（OH）（Piv）_8（MeCN）（HPiv）（H2O）] _ n（1，HPiv是新戊酸）和2-苯甲酰基吡啶（L）在MeCN中的反应生成离子络合物[Mn3 （Piv）5L2（MeCN）]〜+ [Mn6Cl（Piv）i2]〜-o MeCN（3）含有不常见的六核{Mn6（u6-Cl）}阴离子。在复合物[Mn6Cl（ Piv）12] _（NEt_4）〜+ o 5MeCN（4）是由聚合物[Mn（Piv）2（EtOH）]“（2）与NEt4Cl在MeCN中反应制得的。化合物3和4用X表征射线衍射和磁化率。

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来源
《Inorganic Chemistry Communications》 |2007年第9期|共4页
作者
Mikhail A.Kiskin; Grygory G.Aleksandrov; Vladimir N.Ikorskii;
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正文语种 eng
中图分类无机化学;
关键词
Manganese(II) complexes; Pivalate ligands; X-ray structure; Magnetic properties;

机译：锰（II）配合物;新戊酸酯配体;X射线结构;磁性;

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1. First hexanuclear manganese(II) mu_6-Cl centered carboxylate anion:Synthesis,structure and magnetic properties [J] . Mikhail A.Kiskin, Grygory G.Aleksandrov, Vladimir N.Ikorskii Inorganic Chemistry Communications . 2007,第9期

机译：第一六核锰（II）mu_6-Cl中心羧酸根阴离子：合成，结构和磁性
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First hexanuclear manganese(II) mu_6-Cl centered carboxylate anion:Synthesis,structure and magnetic properties

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