Gallium(III) and indium(III) complexes of crossbridged tetraamine ligands

Weijun Niu; Edward H.Wong; Gary R.Weisman; Roger D.Sommer; Arnold L.Rheingold

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Gallium(III) and indium(III) complexes of crossbridged tetraamine ligands

机译：跨桥四胺配体的镓（III）和铟（III）配合物

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Gallium(III) and indium(III) complexes of cross-bridged cyclam and cyclen tetraaza macrocyclic ligand shave been prepared and structurally characterized. In the crystalline state, both the GaCl_3 (cross-bridged cyclam) and InBr_3 (cross-bridged cyclen) complexes feature hexacoordinate cations in cis-folded tetradentate ligand clefts with ancillary cis-dihalides. These represent the first well-characterized gallium and indium halide complexes of tetraazamacryocycles.

机译：制备了桥联的仙客来和周期四氮杂大环配体的镓（III）和铟（III）配合物，并对其结构进行了表征。在结晶状态下，GaCl_3（跨桥的cyclam）和InBr_3（跨桥的cycln）复合物在具有辅助顺式二卤化物的顺式折叠四齿配体裂隙中均具有六配位阳离子。这些代表了四氮杂cr环的第一个特征明确的镓和卤化铟络合物。

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《Inorganic Chemistry Communications》 |2002年第1期|共4页
作者
Weijun Niu; Edward H.Wong; Gary R.Weisman; Roger D.Sommer; Arnold L.Rheingold;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
gallum; indium; cyclam; cyclen; cross-bridged ligands;

机译：镓;铟;环素;环素;跨桥配体;

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Gallium(III) and indium(III) complexes of crossbridged tetraamine ligands

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