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首页> 外文期刊>Inorganic Chemistry Communications >Preparation a new cobalt-containing diphosphine ligand and its reaction towards dicobalt octacarbonyl;X-ray crystal structure of [Co_2(CO)_4(#mu#-CO)_2{#mu#-P,P-(#mu#-PPh_2Cident to CPPh_2)Co_2(CO)_6}]
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Preparation a new cobalt-containing diphosphine ligand and its reaction towards dicobalt octacarbonyl;X-ray crystal structure of [Co_2(CO)_4(#mu#-CO)_2{#mu#-P,P-(#mu#-PPh_2Cident to CPPh_2)Co_2(CO)_6}]

机译:一种新的含钴二膦配体的制备及其与八羰基二钴的反应; [Co_2(CO)_4(#mu#-CO)_2 {#mu#-P,P-(#mu#-PPh_2Cident)的X射线晶体结构到CPPh_2)Co_2(CO)_6}]

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摘要

Consecutive reactions of bis (diphenylphosphino)acetylene with Co_2(CO)_8 resulted in an alkyne-bridged,diphosphine-chelated tetracobalt complex,[Co_2(CO)_4(#mu#-CO)_2{#mu#-P,P-(#mu#-PPh_2Cident to CPPh_2)Co_2(CO)_6}] (2),which has been characterized by spectroscopic means as well as X-ray studies.
机译:双(二苯基膦基)乙炔与Co_2(CO)_8的连续反应导致炔烃桥联,二膦螯合的四钴配合物[Co_2(CO)_4(#mu#-CO)_2 {#mu#-P,P- (#mu#-PPh_2CpPh_2)Co_2(CO)_6}]](2),已通过光谱学方法和X射线研究表征。

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