Hydrothermal synthesis and structural characterization:a novel alpha-Keggin unit supported zinc-bipyridyl complex [Zn(2,2'-bipy)_3]_2[ZnW_(12)O_(40)Zn(2,2'-bipy)_2]·H_2O

Jingyang Niu; Ziliang Wang; Jingping Wang

首页> 外文期刊>Inorganic Chemistry Communications >Hydrothermal synthesis and structural characterization:a novel alpha-Keggin unit supported zinc-bipyridyl complex [Zn(2,2'-bipy)_3]_2[ZnW_(12)O_(40)Zn(2,2'-bipy)_2]·H_2O

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Hydrothermal synthesis and structural characterization:a novel alpha-Keggin unit supported zinc-bipyridyl complex [Zn(2,2'-bipy)_3]_2[ZnW_(12)O_(40)Zn(2,2'-bipy)_2]·H_2O

机译：水热合成和结构表征：一种新型的α-Keggin单元负载的锌-联吡啶络合物[Zn（2,2'-bipy）_3] _2 [ZnW_（12）O_（40）Zn（2,2'-bipy）_2] ·H_2O

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The hydrothermal reaction of Na_2WO_4·2H_2O,ZnCl_2,Zn(Ac)_2·2H_2O,2,2'-bipyridine,and H_2O gives rise to a novel Keggin unit supported zinc-bipyridyl complex [Zn(2,2'-bipy)_3]_2[ZnW_(12)O_(40)Zn(2,2'-bipy)_2]·H_2O consisting of a novel heteropolyanion [ZnW_(12)O_(40)Zn(2,2'-bipy)_2]~(4+) in which the Keggin anion [ZnW_(12)O_(40)]~(6-) acts as a bidentate ligand towards the transition metal cation Zn~(2+) through a terminal oxygen and a bridging oxygen from the same WO_6 octahedron.

机译：Na_2WO_4·2H_2O，ZnCl_2，Zn（Ac）_2·2H_2O，2,2'-联吡啶和H_2O的水热反应产生了新型的Keggin单元支撑的锌-联吡啶络合物[Zn（2,2'-bipy）_3 ] _2 [ZnW_（12）O_（40）Zn（2,2'-bipy）_2]·H_2O由新型杂多阴离子[ZnW_（12）O_（40）Zn（2,2'-bipy）_2]〜（4+），其中Keggin阴离子[ZnW_（12）O_（40）]〜（6-）充当过渡金属阳离子Zn〜（2+）的双齿配体，它们通过末端氧和桥连氧从相同的WO_6八面体。

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《Inorganic Chemistry Communications》 |2003年第9期|共3页
作者
Jingyang Niu; Ziliang Wang; Jingping Wang;
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正文语种 eng
中图分类无机化学;
关键词
hydrothermal synthesis; polyoxometalates; zintungstate; crystal structure;

机译：水热合成;多金属氧酸盐;锌钨酸盐;晶体结构;

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1. Hydrothermal synthesis and structural characterization:a novel alpha-Keggin unit supported zinc-bipyridyl complex [Zn(2,2'-bipy)_3]_2[ZnW_(12)O_(40)Zn(2,2'-bipy)_2]·H_2O [J] . Jingyang Niu, Ziliang Wang, Jingping Wang Inorganic Chemistry Communications . 2003,第9期

机译：水热合成和结构表征：一种新型的α-Keggin单元负载的锌-联吡啶络合物[Zn（2,2'-bipy）_3] _2 [ZnW_（12）O_（40）Zn（2,2'-bipy）_2] ·H_2O
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机译：硅钨酸根阴离子负载的有机-无机杂化配合物[Zn（2,2'-Bipy）3] _（1.5）[SiW_（12）O_（40）Zn（2,2'-Bipy）的合成，结构和表征）2（OH）]·0.25H2O〜1
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机译：α-Keggin单元[Cu（2,2'-bipy）_2] {AlW_（11）〜（VI）W〜vO_（40）[Cu（2,2'- bipy）_2] _2}中心点2H_2O
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Hydrothermal synthesis and structural characterization:a novel alpha-Keggin unit supported zinc-bipyridyl complex [Zn(2,2'-bipy)_3]_2[ZnW_(12)O_(40)Zn(2,2'-bipy)_2]·H_2O

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