K_7{(BO_3)Mn[B_12O_18(OH)_6]}centre dot H_2O:first manganese borate based on covalently linked B_12O_18(OH)_6 clusters and BO_3 units via Mn~(2+)cations

Hong-Xia Zhang; Jie Zhang; Shou-Tian Zheng; Guo-Yu Yang

首页> 外文期刊>Inorganic Chemistry Communications >K_7{(BO_3)Mn[B_12O_18(OH)_6]}centre dot H_2O:first manganese borate based on covalently linked B_12O_18(OH)_6 clusters and BO_3 units via Mn~(2+)cations

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K_7{(BO_3)Mn[B_12O_18(OH)_6]}centre dot H_2O:first manganese borate based on covalently linked B_12O_18(OH)_6 clusters and BO_3 units via Mn~(2+)cations

机译：K_7 {（BO_3）Mn [B_12O_18（OH）_6]}中心点H_2O：基于共价连接的B_12O_18（OH）_6簇和BO_3单元通过Mn〜（2+）阳离子形成的第一硼酸锰

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A novel manganese oxyborate,K_7{(BO_3)[B_12O_18(OH)_6]}centre dot H_2O(1),which is the first example showing the edge-sharing between boron and transition metal,has been solvothermally synthesized.The structure consists of[B_12O_20(OH)_4]and[BO_3]which are linked through unusual MnO5 polyhedron via vertexes and edges.This compound exhibits NLO properties and the intensity of the green light(frequency-doubled output:lambda=532 nm)produced by 1 is as large as that of KDP.

机译：溶剂热合成了硼酸过渡金属K_7 {（BO_3）[B_12O_18（OH）_6]}中心点H_2O（1）的新例子。 [B_12O_20（OH）_4]和[BO_3]通过不寻常的MnO5多面体通过顶点和边缘相连。该化合物具有NLO性质，绿光强度（倍频输出：λ= 532 nm）为1。和KDP一样大

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来源
《Inorganic Chemistry Communications》 |2004年第6期|共3页
作者
Hong-Xia Zhang; Jie Zhang; Shou-Tian Zheng; Guo-Yu Yang;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
manganese; borate; NLO properties;

机译：锰;硼酸盐;NLO性能;

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1. K_7{(BO_3)Mn[B_12O_18(OH)_6]}centre dot H_2O:first manganese borate based on covalently linked B_12O_18(OH)_6 clusters and BO_3 units via Mn~(2+)cations [J] . Hong-Xia Zhang, Jie Zhang, Shou-Tian Zheng, Inorganic Chemistry Communications . 2004,第6期

机译：K_7 {（BO_3）Mn [B_12O_18（OH）_6]}中心点H_2O：基于共价连接的B_12O_18（OH）_6簇和BO_3单元通过Mn〜（2+）阳离子形成的第一硼酸锰
2. Crystal structure of the new borate Li_3Gd(BO_3)_(2 centre dot) Comparison with the homologous Na_3Ln(BO_3)_2 (Ln: La, Nd) compounds [J] . Veronique Jubera, Pierre Gravereau, Jean Pierre Chaminade Solid state sciences . 2001,第4期

机译：新型硼酸盐Li_3Gd（BO_3）_（2中心点）的晶体结构与同源Na_3Ln（BO_3）_2（Ln：La，Nd）化合物的比较
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机译：簇状氰化物桥杂金属配位聚合物：化合物[{Cu_2（dien）_2（CN）} _ 2 {Mo_4Te_4（CN）_（12）}]中心点14.5H_2O和（H_3O）_3K [{Mn（ H_2O）_2} _2 {Mn（H_2O）_2（NO_3）} _ 4 {W_4Te_4（CN）_（12）} _ 2]中心点8H_2
4. Temperature dependence of the sole Mn~(2＋) emissions in Manganese doped ZnS:Mn quantum dots [C] . Xiaosong Zhang, Gaofeng Zhang, Qingsong Huang, International Conference on Micro Nano Devices, Structure and Computing Systems . 2011

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5. Manganese(ii) phosphate nanosheet assembly with native out-of-plane Mn centres for electrocatalytic water oxidation [O] . Hongfei Liu, Xueqing Gao, Xiaolong Yao, 2019

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6. Rhamnogalacturonan-II, a pectic polysaccharide in the walls of growing plant cell, forms a dimer that is covalently cross-linked by a borate ester [O] . O'Neil, Malcolm A., Warrenfeltz, Dennis, Kates, Keith, 1996

机译：Rhamnogalacturonan-II，一种在生长中的植物细胞壁上的果胶多糖，形成一个二聚体，该二聚体通过硼酸酯共价交联

K_7{(BO_3)Mn[B_12O_18(OH)_6]}centre dot H_2O:first manganese borate based on covalently linked B_12O_18(OH)_6 clusters and BO_3 units via Mn~(2+)cations

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