Ni(II),Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol:Formation of coordinated phenoxyl radical

Anastasiya V.Yakovenko; Sergey V.Kolotilov; Anthony W.Addison; Victoria Lopushanskaya

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Ni(II),Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol:Formation of coordinated phenoxyl radical

机译：三（吡唑基）硼酸镍（II），钴（II）和锰（II）与2,6-二叔丁基-4-羧基苯酚的配合物：配位苯氧基的形成

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Ni(II),Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol were synthesized and characterized crystallographically (Ni and Co complexes),spectroscopically and electrochemically.It was found that oxidation of Ni and Co complexes resulted in the formation of coordinated phenoxyl radical and diphenoquinone,whereas only quinone formed in the case of Mn complex and free 2,6-di-tert-butyl-4-carboxy-phenol.

机译：合成了Ni（II），Co（II）和Mn（II）三（吡唑基）硼酸酯与2,6-二叔丁基-4-羧基苯酚的配合物，并进行了晶体学表征（Ni和Co配合物），光谱和发现镍和钴配合物的氧化导致配位的苯氧基自由基和二苯醌的形成，而锰配合物和游离的2,6-二叔丁基-4-羧基苯酚只形成醌。。

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来源
《Inorganic Chemistry Communications》 |2005年第10期|共4页
作者
Anastasiya V.Yakovenko; Sergey V.Kolotilov; Anthony W.Addison; Victoria Lopushanskaya;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
3d-metals; Phenoxyl radical; Tris(pyrazolyl)borates; X-ray structure; ESR spectra; Redox properties;

机译：3d金属;苯氧基;三吡唑硼酸酯;X射线结构;ESR光谱;氧化还原性质;

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1. Ni(II),Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol:Formation of coordinated phenoxyl radical [J] . Anastasiya V.Yakovenko, Sergey V.Kolotilov, Anthony W.Addison, Inorganic Chemistry Communications . 2005,第10期

机译：三（吡唑基）硼酸镍（II），钴（II）和锰（II）与2,6-二叔丁基-4-羧基苯酚的配合物：配位苯氧基的形成
2. Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes [J] . Adam P. Forshaw, † Jeremy M. Smith, † Andrew Ozarowski, Inorganic Chemistry . 2013,第1期

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Ni(II),Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol:Formation of coordinated phenoxyl radical

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