Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer

Yonggang Chen; Mei Wang; Kim Jin; Dongping Wang

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Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer

机译：共价连接Ru（II）三（联吡啶）光敏剂的手性Salen Mn（III）配合物的合成和性能

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摘要

A catalyst-photosensitizer binuclear Mn(III)Ru(II) complex was prepared,in which the catalyst moiety of the Mn(III) unit with a chiral pyrrolidine salen ligand was covalently linked to a photosensitizer of the Ru(II) tris(bipyridyl) fragment.The electrochemical and photophysical properties of the Mn(III)Ru(II) complex were studied.

机译：制备了一种催化剂-光敏剂双核Mn（III）Ru（II）配合物，其中Mn（III）单元的催化剂部分与手性吡咯烷Salen配体共价连接到Ru（II）三（联吡啶）的光敏剂研究了Mn（III）Ru（II）配合物的电化学和光物理性质。

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《Inorganic Chemistry Communications》 |2005年第7期|共4页
作者
Yonggang Chen; Mei Wang; Kim Jin; Dongping Wang;
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正文语种 eng
中图分类无机化学;
关键词
Manganese complex; Ruthenium complex; Heterobinuclear complex; Chiral salen ligand; Pyrrolidine; Light-driven catalyst;

机译：锰配合物钌配合物杂双核配合物手性salen配体吡咯烷光驱动催化剂;

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专利

1. Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer [J] . Yonggang Chen, Mei Wang, Kim Jin, Inorganic Chemistry Communications . 2005,第7期

机译：共价连接Ru（II）三（联吡啶）光敏剂的手性Salen Mn（III）配合物的合成和性能
2. Synthesis of chiral salen Mn(III) complexes covalently inked to Re(I)-based photosensitizers [J] . YONGGANG CHEN, MEI WANG, KUN JIN Journal of Coordination Chemistry . 2006,第5期

机译：与基于Re（I）的光敏剂共价结合的手性Salen Mn（III）配合物的合成
3. Molecule-based magnets formed by bimetallic three-dimensional oxalate networks and chiral tris(bipyridyl) complex cations. The series [Z(II)(bpy)(3)][ClO4][(MCrIII)-Cr-II(ox)(3)] (Z(II) = Ru, Fe, Co, and Ni; M-II = Mn, Fe, Co, Ni, Cu, and Zn; ox = ox [J] . Coronado E., Gomez-Garcia CJ., Martinez-Agudo JM., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第1期

机译：由双金属三维草酸盐网络和手性三（联吡啶基）络合物阳离子形成的分子基磁体。系列[Z（II）（bpy）（3）] [ClO4] [（MCrIII）-Cr-II（ox）（3）]（Z（II）= Ru，Fe，Co和Ni; M-II =锰，铁，钴，镍，铜和锌;牛=牛
4. Synthesis and Catalytic Study of Magnetic Separable Catalyst: M(Salen)-Functionalized Fe_3O_4 Polymer Composite Materials (M = Ru(III), Cu(II), Fe(III)) [C] . Hao-Yu Shen, Sheng-Dong Pan, Fang Fang International Conference on Manufacturing Science and Engineering . 2011

机译：磁性可分离催化剂的合成与催化研究：M（盐） - 官能化Fe_3O_4聚合物复合材料（M = Ru（III），Cu（II），Fe（III））
5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

机译：Ru和Mn的一系列高价羰基配合物的结构和反应性：Ru（III）介导的三苯膦催化氧化，双核Mn（III，III）和Mn（III，IV）二聚体的表征以及单核铁（III）和铁（IV）。
6. Chiral MnIII (Salen) Covalently Bonded on Modified ZPS-PVPA and ZPS-IPPA as Efficient Catalysts for Enantioselective Epoxidation of Unfunctionalized Olefins [O] . Xiaochuan Zou, Cun Wang, Yue Wang, 2017

机译：手性MnIII（Salen）共价键合在修饰的ZPS-PVPA和ZPS-IPPA上作为未官能化烯烃对映选择性环氧化的高效催化剂
7. Correction: Tri- and hexa-nuclear NiII–MnII complexes of a N2O2 donor unsymmetrical ligand: synthesis, structures, magnetic properties and catalytic oxidase activities [O] . Prithwish Mahapatra, Michael G. B. Drew, Ashutosh Ghosh 2020

机译：校正：N2O2供体非对称配体的三核和六核核NIII-MNII复合物：合成，结构，磁性和催化氧化酶活性
8. Oxidative and Electrophilic Pathways in the Reactions of Organochromium(III) Complexes with Nitrous Acid and Tris(2,2'-Bipyridyl) Ruthenium(III) [R] . Melton, J. D. 1986

机译：有机铬（III）配合物与亚硝酸和三（2,2'-联吡啶）钌（III）反应中的氧化和亲电通路

Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer

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