Synthesis,crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {Ni~(II)(Me6-[14]ane-N4)}2[W~(IV)(CN)8] · 6H2O

Hu Zhou; Ai-Hua Yuan; Xiao-Ping Shen

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Synthesis,crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {Ni~(II)(Me6-[14]ane-N4)}2[W~(IV)(CN)8] · 6H2O

机译：三维氰基桥杂金属配合物{Ni〜（II）（Me6- [14] ane-N4）} 2 [W〜（IV）（CN）8]·6H2O的合成，晶体结构和磁性

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Self-assembly of [W(CN)_8]~(4-)and {Ni(Me6-[14]ane-N4)}~(2+)(Me6-[14]ane-N4 = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclote-tradecane)leads to a novel three-dimensional cyano-bridged complex {Ni(Me6-[14]ane-N4)}2[W(CN)_8] · 6H2O(1),which was characterized by IR,elemental analysis,ICP,TGA and SC-XRD.Magnetic behavior of the complex shows a characteristic of combination of zero-field splitting of Ni~(2+)in an axially distorted octahedral surrounding and a weak antiferromagnetic interaction between Ni~(2+)ions through the diamagnetic [W(CN)_8]~(4-)bridges.

机译：[W（CN）_8]〜（4-）和{Ni（Me6- [14] ane-N4）}〜（2 +）（Me6- [14] ane-N4 = 5,7,7的自组装，12,14,14-六甲基-1,4,8,11-四氮杂杂环戊烯）导致了新型的三维氰基桥联络合物{Ni（Me6- [14] ane-N4）} 2 [W（CN ）_8]·6H2O（1），通过IR，元素分析，ICP，TGA和SC-XRD表征。配合物的磁性表现为Ni〜（2+）零场分裂的组合特征。轴向扭曲的八面体周围环境和通过抗磁性[W（CN）_8]〜（4-）桥的Ni〜（2+）离子之间的弱反铁磁相互作用。

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《Inorganic Chemistry Communications》 |2007年第8期|共4页
作者
Hu Zhou; Ai-Hua Yuan; Xiao-Ping Shen;
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正文语种 eng
中图分类无机化学;
关键词
Octacyanotungstate; Nickel(II)complex; Crystal structure; Magnetic properties;

机译：八氰基钨酸盐;镍（II）配合物;晶体结构;磁性;

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1. Synthesis,crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {Ni~(II)(Me6-[14]ane-N4)}2[W~(IV)(CN)8] · 6H2O [J] . Hu Zhou, Ai-Hua Yuan, Xiao-Ping Shen Inorganic Chemistry Communications . 2007,第8期

机译：三维氰基桥杂金属配合物{Ni〜（II）（Me6- [14] ane-N4）} 2 [W〜（IV）（CN）8]·6H2O的合成，晶体结构和磁性
2. Synthesis, crystal structure and magnetic properties of a new three-dimensional cyano-bridged Ni(II)-Mo(IV) complex [J] . Hu Zhou, Ying-Ying Chen, Ai-Hua Yuan Inorganic Chemistry Communications . 2008,第4期

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4. Synthesis and magnetic properties of octacyanotungstate-based magnet Mn~(II)Fe~(II)W~(IV)(CN)_8·8H_2O [C] . Yun He, Qing Lin, Jinpei Lin, Symposia on Electromagnetic and Electronic Engineering . 2015

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Synthesis,crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {Ni~(II)(Me6-[14]ane-N4)}2[W~(IV)(CN)8] · 6H2O

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